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Oxygen stoichiometry of low-temperature synthesized metastableT′-La2CuO4

Hord, R. ; Pascua, G. ; Hofmann, K. ; Cordier, G. ; Kurian, J. ; Luetkens, H. ; Pomjakushin, V. ; Reehuis, M. ; Albert, Barbara ; Alff, L. (2013)
Oxygen stoichiometry of low-temperature synthesized metastableT′-La2CuO4.
In: Superconductor Science and Technology, 26 (10)
doi: 10.1088/0953-2048/26/10/105026
Artikel, Bibliographie

Kurzbeschreibung (Abstract)

We have investigated the oxygen stoichiometry of low-temperature synthesized metastable T'-La2CuO4 bulk samples by neutron scattering. T'-La2CuO4 is the parent compound of electron-doped high-temperature superconductors that is chemically closest to the parent compound of the hole-doped superconductor T-La2CuO4. While usually all electron-doped cuprates require strong reduction to approach stoichiometry, the low-temperature synthesis directly yields fully stoichiometric compounds. This result makes low-temperature grown T'-La2CuO4 the ideal material to perform a comparison of the two parent compounds of hole- and electron-doped cuprates.

Typ des Eintrags: Artikel
Erschienen: 2013
Autor(en): Hord, R. ; Pascua, G. ; Hofmann, K. ; Cordier, G. ; Kurian, J. ; Luetkens, H. ; Pomjakushin, V. ; Reehuis, M. ; Albert, Barbara ; Alff, L.
Art des Eintrags: Bibliographie
Titel: Oxygen stoichiometry of low-temperature synthesized metastableT′-La2CuO4
Sprache: Englisch
Publikationsjahr: Oktober 2013
Verlag: IOP Publishing
Titel der Zeitschrift, Zeitung oder Schriftenreihe: Superconductor Science and Technology
Jahrgang/Volume einer Zeitschrift: 26
(Heft-)Nummer: 10
DOI: 10.1088/0953-2048/26/10/105026
Kurzbeschreibung (Abstract):

We have investigated the oxygen stoichiometry of low-temperature synthesized metastable T'-La2CuO4 bulk samples by neutron scattering. T'-La2CuO4 is the parent compound of electron-doped high-temperature superconductors that is chemically closest to the parent compound of the hole-doped superconductor T-La2CuO4. While usually all electron-doped cuprates require strong reduction to approach stoichiometry, the low-temperature synthesis directly yields fully stoichiometric compounds. This result makes low-temperature grown T'-La2CuO4 the ideal material to perform a comparison of the two parent compounds of hole- and electron-doped cuprates.

Freie Schlagworte: Superconductivity
Fachbereich(e)/-gebiet(e): 11 Fachbereich Material- und Geowissenschaften
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Dünne Schichten
07 Fachbereich Chemie
07 Fachbereich Chemie > Eduard Zintl-Institut > Fachgebiet Anorganische Chemie
Hinterlegungsdatum: 09 Jan 2014 09:32
Letzte Änderung: 04 Mär 2020 12:14
PPN:
Sponsoren: This work was supported by DFG (Deutsche Forschungsgemeinschaft) Grant Nos Al536/9 and Al560/9.
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