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Biodegradable cellular polylactic acid ferroelectrets with strong longitudinal and transverse piezoelectricity

Zhukov, Sergey ; Ma, Xingchen ; Seggern, Heinz von ; Sessler, Gerhard M. ; Dali, Omar Ben ; Kupnik, Mario ; Zhang, Xiaoqing (2024)
Biodegradable cellular polylactic acid ferroelectrets with strong longitudinal and transverse piezoelectricity.
In: Applied Physics Letters, 2020, 117 (11)
doi: 10.26083/tuprints-00027715
Artikel, Zweitveröffentlichung, Verlagsversion

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Kurzbeschreibung (Abstract)

Polymers with electrically charged internal air cavities (ferroelectrets) reveal a pronounced piezoelectric response and are regarded as soft electroactive multi-functional materials. This work presents preliminary results on the preparation and piezoelectric effect of ferroelectrets based on the polylactic acid (PLA) polymer. A distinctive feature of the manufactured films is that they are biodegradable. After a microstructure modification of carbon dioxide (CO2) foamed PLA sheets by hot-pressing treatment and corona polarization, these cellular films reveal large piezoelectric d₃₃ and d₃₁ responses in both quasi-static and dynamic modes. For freshly charged films, the maximum quasi-static piezoelectric coefficients are about 600 pC/N (d₃₃⁠⁠) and 44 pC/N (d₃₁⁠⁠) for a relatively thick film of 360 μm and a nominal porosity of about 60%. During the first 20 days after polarization, the piezoelectric activity decreases by half compared to the primary value, but then remains almost unchanged for a long time. Due to an already established inherent biocompatibility of PLA polymers, these eco-friendly ferroelectrets can be potentially used in various biological applications such as biosensors and microenergy harvesters embedded in tissue and artificial muscles.

Typ des Eintrags: Artikel
Erschienen: 2024
Autor(en): Zhukov, Sergey ; Ma, Xingchen ; Seggern, Heinz von ; Sessler, Gerhard M. ; Dali, Omar Ben ; Kupnik, Mario ; Zhang, Xiaoqing
Art des Eintrags: Zweitveröffentlichung
Titel: Biodegradable cellular polylactic acid ferroelectrets with strong longitudinal and transverse piezoelectricity
Sprache: Englisch
Publikationsjahr: 13 September 2024
Ort: Darmstadt
Publikationsdatum der Erstveröffentlichung: 17 September 2020
Ort der Erstveröffentlichung: Melville, NY
Verlag: AIP Publishing
Titel der Zeitschrift, Zeitung oder Schriftenreihe: Applied Physics Letters
Jahrgang/Volume einer Zeitschrift: 117
(Heft-)Nummer: 11
Kollation: 6 Seiten
DOI: 10.26083/tuprints-00027715
URL / URN: https://tuprints.ulb.tu-darmstadt.de/27715
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Herkunft: Zweitveröffentlichungsservice
Kurzbeschreibung (Abstract):

Polymers with electrically charged internal air cavities (ferroelectrets) reveal a pronounced piezoelectric response and are regarded as soft electroactive multi-functional materials. This work presents preliminary results on the preparation and piezoelectric effect of ferroelectrets based on the polylactic acid (PLA) polymer. A distinctive feature of the manufactured films is that they are biodegradable. After a microstructure modification of carbon dioxide (CO2) foamed PLA sheets by hot-pressing treatment and corona polarization, these cellular films reveal large piezoelectric d₃₃ and d₃₁ responses in both quasi-static and dynamic modes. For freshly charged films, the maximum quasi-static piezoelectric coefficients are about 600 pC/N (d₃₃⁠⁠) and 44 pC/N (d₃₁⁠⁠) for a relatively thick film of 360 μm and a nominal porosity of about 60%. During the first 20 days after polarization, the piezoelectric activity decreases by half compared to the primary value, but then remains almost unchanged for a long time. Due to an already established inherent biocompatibility of PLA polymers, these eco-friendly ferroelectrets can be potentially used in various biological applications such as biosensors and microenergy harvesters embedded in tissue and artificial muscles.

Freie Schlagworte: Piezoelectricity, Polymers, Porous media, Biomaterials, Thin films, Biosensors
Status: Verlagsversion
URN: urn:nbn:de:tuda-tuprints-277150
Sachgruppe der Dewey Dezimalklassifikatin (DDC): 600 Technik, Medizin, angewandte Wissenschaften > 621.3 Elektrotechnik, Elektronik
Fachbereich(e)/-gebiet(e): 11 Fachbereich Material- und Geowissenschaften
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft
18 Fachbereich Elektrotechnik und Informationstechnik
18 Fachbereich Elektrotechnik und Informationstechnik > Mess- und Sensortechnik
Hinterlegungsdatum: 13 Sep 2024 13:44
Letzte Änderung: 16 Sep 2024 05:36
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