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Effect of Silica Fume on Metakaolin Geopolymers’ Sulfuric Acid Resistance

Vogt, Oliver ; Ukrainczyk, Neven ; Koenders, Eddie (2022)
Effect of Silica Fume on Metakaolin Geopolymers’ Sulfuric Acid Resistance.
In: Materials, 14 (18)
doi: 10.3390/ma14185396
Artikel, Bibliographie

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Kurzbeschreibung (Abstract)

To demonstrate the importance of the Si/Al ratio in terms of geopolymer mix designs for acid resistance, a metakaolin-based geopolymer was modified by replacing the aforementioned precursor with different percentages of silica fume. Durability tests were performed by exposing geopolymers with varying amounts of silica fume (up to 9%) to sulfuric acid solution (pH 1) over a period of 84 days. Geopolymer samples were analyzed by X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR) and scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDX) before and after 7, 14, 28, 56 and 84 days of exposure. To show the time-dependent change of the elemental composition in the corroded layer after sulfuric acid attack, SEM-EDX elemental mappings were conducted and divided into 100 µm segments to generate element-specific depth profiles. The results show that above a critical silica fume content, the erosion of the sample surface by complete dissolution can be prevented and higher amounts of silica fume lead to a significant densification of large (protective) areas of the corroded layer, which delays the progress of corrosion.

Typ des Eintrags: Artikel
Erschienen: 2022
Autor(en): Vogt, Oliver ; Ukrainczyk, Neven ; Koenders, Eddie
Art des Eintrags: Bibliographie
Titel: Effect of Silica Fume on Metakaolin Geopolymers’ Sulfuric Acid Resistance
Sprache: Englisch
Publikationsjahr: 2022
Verlag: MDPI
Titel der Zeitschrift, Zeitung oder Schriftenreihe: Materials
Jahrgang/Volume einer Zeitschrift: 14
(Heft-)Nummer: 18
Kollation: 26 Seiten
DOI: 10.3390/ma14185396
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Kurzbeschreibung (Abstract):

To demonstrate the importance of the Si/Al ratio in terms of geopolymer mix designs for acid resistance, a metakaolin-based geopolymer was modified by replacing the aforementioned precursor with different percentages of silica fume. Durability tests were performed by exposing geopolymers with varying amounts of silica fume (up to 9%) to sulfuric acid solution (pH 1) over a period of 84 days. Geopolymer samples were analyzed by X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR) and scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDX) before and after 7, 14, 28, 56 and 84 days of exposure. To show the time-dependent change of the elemental composition in the corroded layer after sulfuric acid attack, SEM-EDX elemental mappings were conducted and divided into 100 µm segments to generate element-specific depth profiles. The results show that above a critical silica fume content, the erosion of the sample surface by complete dissolution can be prevented and higher amounts of silica fume lead to a significant densification of large (protective) areas of the corroded layer, which delays the progress of corrosion.

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Keywords: geopolymer; metakaolin; silica fume; sulfuric acid attack; corrosion; durability; SEM-EDX

Sachgruppe der Dewey Dezimalklassifikatin (DDC): 600 Technik, Medizin, angewandte Wissenschaften > 600 Technik
Fachbereich(e)/-gebiet(e): 13 Fachbereich Bau- und Umweltingenieurwissenschaften
13 Fachbereich Bau- und Umweltingenieurwissenschaften > Institut für Werkstoffe im Bauwesen
Hinterlegungsdatum: 02 Aug 2024 12:41
Letzte Änderung: 02 Aug 2024 12:41
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