Yamaki, T. ; Nuryanthi, N. ; Koshikawa, H. ; Asano, M. ; Sawada, S. ; Hakoda, T. ; Maekawa, Y. ; Voss, K.-O. ; Severin, D. ; Seidl, T. ; Trautmann, C. ; Neumann, R. (2013)
Ion-track membranes of fluoropolymers: toward controlling the pore size and shape.
In: Nuclear Instruments and Methods in Physics Research. Section B: Beam Interactions with Materials and Atoms, 314
doi: 10.1016/j.nimb.2013.05.028
Artikel, Bibliographie
Kurzbeschreibung (Abstract)
The possibility of varying the beam parameters and applying the effect of a pre-etching treatment for poly(vinylidene fluoride) (PVDF) ion-track membranes was investigated with the goal of achieving enhanced track etching for effective control of the pore size and shape. Commercially available 25 μm-thick PVDF films were irradiated at room temperature with swift heavy ions from the JAEA’s TIARA cyclotron and GSI’s UNILAC linear accelerator. Irradiation with a higher linear energy transfer (LET) beam gave faster track etching and larger pores, suggesting that the LET could be the most crucial factor determining the pore size. In-situ infra-red absorption and residual gas analyses shed light on the detailed chemistry of not only the ion-induced degradation, but also post-irradiation reactions. The pre-etching treatment effect involved oxidation of the unsaturated bonds within the latent track, which accelerated the chemical dissolution for efficient pore evolution. In other words, exposure to a gaseous oxidant, i.e., ozone, shortened the breakthrough time.
| Typ des Eintrags: | Artikel |
|---|---|
| Erschienen: | 2013 |
| Autor(en): | Yamaki, T. ; Nuryanthi, N. ; Koshikawa, H. ; Asano, M. ; Sawada, S. ; Hakoda, T. ; Maekawa, Y. ; Voss, K.-O. ; Severin, D. ; Seidl, T. ; Trautmann, C. ; Neumann, R. |
| Art des Eintrags: | Bibliographie |
| Titel: | Ion-track membranes of fluoropolymers: toward controlling the pore size and shape |
| Sprache: | Englisch |
| Publikationsjahr: | 1 November 2013 |
| Verlag: | Elsevier |
| Titel der Zeitschrift, Zeitung oder Schriftenreihe: | Nuclear Instruments and Methods in Physics Research. Section B: Beam Interactions with Materials and Atoms |
| Jahrgang/Volume einer Zeitschrift: | 314 |
| DOI: | 10.1016/j.nimb.2013.05.028 |
| Kurzbeschreibung (Abstract): | The possibility of varying the beam parameters and applying the effect of a pre-etching treatment for poly(vinylidene fluoride) (PVDF) ion-track membranes was investigated with the goal of achieving enhanced track etching for effective control of the pore size and shape. Commercially available 25 μm-thick PVDF films were irradiated at room temperature with swift heavy ions from the JAEA’s TIARA cyclotron and GSI’s UNILAC linear accelerator. Irradiation with a higher linear energy transfer (LET) beam gave faster track etching and larger pores, suggesting that the LET could be the most crucial factor determining the pore size. In-situ infra-red absorption and residual gas analyses shed light on the detailed chemistry of not only the ion-induced degradation, but also post-irradiation reactions. The pre-etching treatment effect involved oxidation of the unsaturated bonds within the latent track, which accelerated the chemical dissolution for efficient pore evolution. In other words, exposure to a gaseous oxidant, i.e., ozone, shortened the breakthrough time. |
| Freie Schlagworte: | ion-track membrane, poly(vinylidene fluoride) (PVDF), ion beam, linear energy transfer (LET), pre-etching treatment |
| Fachbereich(e)/-gebiet(e): | 11 Fachbereich Material- und Geowissenschaften 11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft 11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Ionenstrahlmodifizierte Materialien |
| Hinterlegungsdatum: | 18 Mär 2024 07:52 |
| Letzte Änderung: | 18 Mär 2024 07:52 |
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