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Geopolymer, Calcium Aluminate, and Portland Cement-Based Mortars: Comparing Degradation Using Acetic Acid

Ukrainczyk, Neven ; Muthu, Murugan ; Vogt, Oliver ; Koenders, Eddie (2024)
Geopolymer, Calcium Aluminate, and Portland Cement-Based Mortars: Comparing Degradation Using Acetic Acid.
In: Materials, 2019, 12 (19)
doi: 10.26083/tuprints-00016237
Artikel, Zweitveröffentlichung, Verlagsversion

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Kurzbeschreibung (Abstract)

In this paper, we comparitvley studied acetic acid attacks on geopolymer (GP-M), calcium aluminate (CAC-M), and Portland cement (PC-M)-based mortars. Consequent formations of deteriorated or transition layers surrounding the unaltered core material was classified in these three mortars, according to different degradation levels depending on what binder type was involved. Apart from mass loss, hardness, and deterioration depth, their microstructural alterations were analyzed using test methods such as scanning electron microscopy with energy dispersive spectroscopy (SEM-EDS), mercury intrusion porosimetry (MIP), powder X-ray diffraction (XRD), and thermogravimetric analysis-differential scanning calorimeter (TGA-DSC), which showed the different mechanisms for each binder type. Elemental maps revealed the decalcification (PC-M and CAC-M) and depolymerization (GP-M) that occurred across the mortar sections. The mass loss, hardness, and porosity were the least affected for GP-M, followed by CAC-M. These results points out that geopolymer-based mortars have improved acid resistance, which can be used as a potential alternative to conventional cement concretes that have been exposed to agro-industrial environments.

Typ des Eintrags: Artikel
Erschienen: 2024
Autor(en): Ukrainczyk, Neven ; Muthu, Murugan ; Vogt, Oliver ; Koenders, Eddie
Art des Eintrags: Zweitveröffentlichung
Titel: Geopolymer, Calcium Aluminate, and Portland Cement-Based Mortars: Comparing Degradation Using Acetic Acid
Sprache: Englisch
Publikationsjahr: 16 Januar 2024
Ort: Darmstadt
Publikationsdatum der Erstveröffentlichung: 2019
Ort der Erstveröffentlichung: Basel
Verlag: MDPI
Titel der Zeitschrift, Zeitung oder Schriftenreihe: Materials
Jahrgang/Volume einer Zeitschrift: 12
(Heft-)Nummer: 19
Kollation: 12 Seiten
DOI: 10.26083/tuprints-00016237
URL / URN: https://tuprints.ulb.tu-darmstadt.de/16237
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Herkunft: Zweitveröffentlichung DeepGreen
Kurzbeschreibung (Abstract):

In this paper, we comparitvley studied acetic acid attacks on geopolymer (GP-M), calcium aluminate (CAC-M), and Portland cement (PC-M)-based mortars. Consequent formations of deteriorated or transition layers surrounding the unaltered core material was classified in these three mortars, according to different degradation levels depending on what binder type was involved. Apart from mass loss, hardness, and deterioration depth, their microstructural alterations were analyzed using test methods such as scanning electron microscopy with energy dispersive spectroscopy (SEM-EDS), mercury intrusion porosimetry (MIP), powder X-ray diffraction (XRD), and thermogravimetric analysis-differential scanning calorimeter (TGA-DSC), which showed the different mechanisms for each binder type. Elemental maps revealed the decalcification (PC-M and CAC-M) and depolymerization (GP-M) that occurred across the mortar sections. The mass loss, hardness, and porosity were the least affected for GP-M, followed by CAC-M. These results points out that geopolymer-based mortars have improved acid resistance, which can be used as a potential alternative to conventional cement concretes that have been exposed to agro-industrial environments.

Freie Schlagworte: geopolymer, Portland cement, calcium aluminate cement, leaching, microstructure, deterioration, acetic acid attack, SEM-EDS
Status: Verlagsversion
URN: urn:nbn:de:tuda-tuprints-162378
Zusätzliche Informationen:

This article belongs to the Section Construction and Building Materials

Sachgruppe der Dewey Dezimalklassifikatin (DDC): 600 Technik, Medizin, angewandte Wissenschaften > 624 Ingenieurbau und Umwelttechnik
600 Technik, Medizin, angewandte Wissenschaften > 660 Technische Chemie
Fachbereich(e)/-gebiet(e): 13 Fachbereich Bau- und Umweltingenieurwissenschaften
13 Fachbereich Bau- und Umweltingenieurwissenschaften > Institut für Werkstoffe im Bauwesen
Hinterlegungsdatum: 16 Jan 2024 12:13
Letzte Änderung: 17 Jan 2024 14:50
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