Perko, Janez ; Ukrainczyk, Neven ; Šavija, Branko ; Phung, Quoc Tri ; Koenders, Eddie A. B. (2024)
Influence of Micro-Pore Connectivity and Micro-Fractures on Calcium Leaching of Cement Pastes — A Coupled Simulation Approach.
In: Materials, 2020, 13 (12)
doi: 10.26083/tuprints-00016970
Artikel, Zweitveröffentlichung, Verlagsversion
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Kurzbeschreibung (Abstract)
A coupled numerical approach is used to evaluate the influence of pore connectivity and microcracks on leaching kinetics in fully saturated cement paste. The unique advantage of the numerical model is the ability to construct and evaluate a material with controlled properties, which is very difficult under experimental conditions. Our analysis is based on two virtual microstructures, which are different in terms of pore connectivity but the same in terms of porosity and the amount of solid phases. Numerical fracturing was performed on these microstructures. The non-fractured and fractured microstructures were both subjected to chemical leaching. Results show that despite very different material physical properties, for example, pore connectivity and effective diffusivity, the leaching kinetics remain the same as long as the amount of soluble phases, i.e., buffering capacity, is the same. The leaching kinetics also remains the same in the presence of microcracks.
| Typ des Eintrags: | Artikel |
|---|---|
| Erschienen: | 2024 |
| Autor(en): | Perko, Janez ; Ukrainczyk, Neven ; Šavija, Branko ; Phung, Quoc Tri ; Koenders, Eddie A. B. |
| Art des Eintrags: | Zweitveröffentlichung |
| Titel: | Influence of Micro-Pore Connectivity and Micro-Fractures on Calcium Leaching of Cement Pastes — A Coupled Simulation Approach |
| Sprache: | Englisch |
| Publikationsjahr: | 15 Januar 2024 |
| Ort: | Darmstadt |
| Publikationsdatum der Erstveröffentlichung: | 2020 |
| Ort der Erstveröffentlichung: | Basel |
| Verlag: | MDPI |
| Titel der Zeitschrift, Zeitung oder Schriftenreihe: | Materials |
| Jahrgang/Volume einer Zeitschrift: | 13 |
| (Heft-)Nummer: | 12 |
| Kollation: | 23 Seiten |
| DOI: | 10.26083/tuprints-00016970 |
| URL / URN: | https://tuprints.ulb.tu-darmstadt.de/16970 |
| Zugehörige Links: | |
| Herkunft: | Zweitveröffentlichung DeepGreen |
| Kurzbeschreibung (Abstract): | A coupled numerical approach is used to evaluate the influence of pore connectivity and microcracks on leaching kinetics in fully saturated cement paste. The unique advantage of the numerical model is the ability to construct and evaluate a material with controlled properties, which is very difficult under experimental conditions. Our analysis is based on two virtual microstructures, which are different in terms of pore connectivity but the same in terms of porosity and the amount of solid phases. Numerical fracturing was performed on these microstructures. The non-fractured and fractured microstructures were both subjected to chemical leaching. Results show that despite very different material physical properties, for example, pore connectivity and effective diffusivity, the leaching kinetics remain the same as long as the amount of soluble phases, i.e., buffering capacity, is the same. The leaching kinetics also remains the same in the presence of microcracks. |
| Freie Schlagworte: | numerical models, pore scale, cement leaching, micro-fractures, pore connectivity, effective diffusivity |
| Status: | Verlagsversion |
| URN: | urn:nbn:de:tuda-tuprints-169707 |
| Zusätzliche Informationen: | This article belongs to the Special Issue Modeling of Cementitious Materials and Structures |
| Sachgruppe der Dewey Dezimalklassifikatin (DDC): | 600 Technik, Medizin, angewandte Wissenschaften > 624 Ingenieurbau und Umwelttechnik |
| Fachbereich(e)/-gebiet(e): | 13 Fachbereich Bau- und Umweltingenieurwissenschaften 13 Fachbereich Bau- und Umweltingenieurwissenschaften > Institut für Werkstoffe im Bauwesen |
| Hinterlegungsdatum: | 15 Jan 2024 14:15 |
| Letzte Änderung: | 16 Jan 2024 07:53 |
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| Suche nach Titel in: | TUfind oder in Google |
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- Influence of Micro-Pore Connectivity and Micro-Fractures on Calcium Leaching of Cement Pastes — A Coupled Simulation Approach. (deposited 15 Jan 2024 14:15) [Gegenwärtig angezeigt]
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