Ukrainczyk, Neven ; Thiedeitz, Mareike ; Kränkel, Thomas ; Koenders, Eddie ; Gehlen, Christoph (2024)
Modeling SAOS Yield Stress of Cement Suspensions: Microstructure-Based Computational Approach.
In: Materials, 2020, 13 (12)
doi: 10.26083/tuprints-00016976
Artikel, Zweitveröffentlichung, Verlagsversion
 | Es ist eine neuere Version dieses Eintrags verfügbar. |
Kurzbeschreibung (Abstract)
Two static yield stress models, one known as YODEL and the newly proposed BreakPro, based on inter-particle bond breaking probability, were employed to comparatively simulate the yield stress of cement suspensions, induced by oscillatory rheological tests with small amplitude oscillatory shear (SAOS). This yield stress occurs at a critical strain in the order of 0.01%, and is commonly attributed to the limit of the linear viscoelastic domain, where attractive forces bridge the cement particles and form a flocculated particle network. YODEL is based on van der Waals (vdW) interaction forces to describe the yield stress for flow onset at a critical strain of a few percent, developed for simple non-reactive particulate suspensions. However, due to the high pH and reactivity of cementitious suspensions, their particle interaction forces are much higher than vdW. Therefore, until now, the YODEL adaptations to cementitious suspensions did not explicitly consider the microstructural-based salient feature of the original model, but used it as an implicit fitting parameter to scale the average attractive force. In this paper, the force is inversely estimated using the full power of the two microstructural-based models, presenting a new mathematical tool for investigating the fragility of the rigid percolated structure of cement suspensions. The model parameters were calibrated on measured yield stresses obtained by SAOS measurements in a high-sensitivity rheometer. The estimated forces were found to be 5.57 (BreakPro) and 1.43 (YODEL) times higher than typical van der Waals forces. The YODEL percolation threshold of 21% turned out to be significantly lower than the one found by the BreakPro model (37%). This indicated that BreakPro modeling assumptions are better suited for the description of yield stress at SAOS critical strain than the YODEL model.
| Typ des Eintrags: | Artikel |
|---|---|
| Erschienen: | 2024 |
| Autor(en): | Ukrainczyk, Neven ; Thiedeitz, Mareike ; Kränkel, Thomas ; Koenders, Eddie ; Gehlen, Christoph |
| Art des Eintrags: | Zweitveröffentlichung |
| Titel: | Modeling SAOS Yield Stress of Cement Suspensions: Microstructure-Based Computational Approach |
| Sprache: | Englisch |
| Publikationsjahr: | 15 Januar 2024 |
| Ort: | Darmstadt |
| Publikationsdatum der Erstveröffentlichung: | 2020 |
| Ort der Erstveröffentlichung: | Basel |
| Verlag: | MDPI |
| Titel der Zeitschrift, Zeitung oder Schriftenreihe: | Materials |
| Jahrgang/Volume einer Zeitschrift: | 13 |
| (Heft-)Nummer: | 12 |
| Kollation: | 17 Seiten |
| DOI: | 10.26083/tuprints-00016976 |
| URL / URN: | https://tuprints.ulb.tu-darmstadt.de/16976 |
| Zugehörige Links: | |
| Herkunft: | Zweitveröffentlichung DeepGreen |
| Kurzbeschreibung (Abstract): | Two static yield stress models, one known as YODEL and the newly proposed BreakPro, based on inter-particle bond breaking probability, were employed to comparatively simulate the yield stress of cement suspensions, induced by oscillatory rheological tests with small amplitude oscillatory shear (SAOS). This yield stress occurs at a critical strain in the order of 0.01%, and is commonly attributed to the limit of the linear viscoelastic domain, where attractive forces bridge the cement particles and form a flocculated particle network. YODEL is based on van der Waals (vdW) interaction forces to describe the yield stress for flow onset at a critical strain of a few percent, developed for simple non-reactive particulate suspensions. However, due to the high pH and reactivity of cementitious suspensions, their particle interaction forces are much higher than vdW. Therefore, until now, the YODEL adaptations to cementitious suspensions did not explicitly consider the microstructural-based salient feature of the original model, but used it as an implicit fitting parameter to scale the average attractive force. In this paper, the force is inversely estimated using the full power of the two microstructural-based models, presenting a new mathematical tool for investigating the fragility of the rigid percolated structure of cement suspensions. The model parameters were calibrated on measured yield stresses obtained by SAOS measurements in a high-sensitivity rheometer. The estimated forces were found to be 5.57 (BreakPro) and 1.43 (YODEL) times higher than typical van der Waals forces. The YODEL percolation threshold of 21% turned out to be significantly lower than the one found by the BreakPro model (37%). This indicated that BreakPro modeling assumptions are better suited for the description of yield stress at SAOS critical strain than the YODEL model. |
| Freie Schlagworte: | cement paste, rheology, small amplitude oscillatory shear (SAOS), yield stress, mathematical modeling |
| Status: | Verlagsversion |
| URN: | urn:nbn:de:tuda-tuprints-169766 |
| Zusätzliche Informationen: | This article belongs to the Special Issue Rheology of Reactive, Multiscale, Multiphase Construction Materials |
| Sachgruppe der Dewey Dezimalklassifikatin (DDC): | 600 Technik, Medizin, angewandte Wissenschaften > 624 Ingenieurbau und Umwelttechnik |
| Fachbereich(e)/-gebiet(e): | 13 Fachbereich Bau- und Umweltingenieurwissenschaften 13 Fachbereich Bau- und Umweltingenieurwissenschaften > Institut für Werkstoffe im Bauwesen |
| Hinterlegungsdatum: | 15 Jan 2024 14:11 |
| Letzte Änderung: | 16 Jan 2024 08:18 |
| PPN: | |
| Export: | |
| Suche nach Titel in: | TUfind oder in Google |
Verfügbare Versionen dieses Eintrags
- Modeling SAOS Yield Stress of Cement Suspensions: Microstructure-Based Computational Approach. (deposited 15 Jan 2024 14:11) [Gegenwärtig angezeigt]
 |
Frage zum Eintrag |
Optionen (nur für Redakteure)
 |
Redaktionelle Details anzeigen |
Drucken
Impressum