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Mechanical tailoring of dislocation densities in SrTiO3 at room temperature

Okafor, Chukwudalu ; Ding, Kuan ; Zhou, Xiandong ; Durst, Karsten ; Rödel, Jürgen ; Fang, Xufei (2022)
Mechanical tailoring of dislocation densities in SrTiO3 at room temperature.
In: Journal of the American Ceramic Society, 105 (4)
doi: 10.1111/jace.18277
Artikel, Bibliographie

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Kurzbeschreibung (Abstract)

Dislocation-tuned functional properties such as electrical conductivity, thermal conductivity, and ferroelectric properties in oxides are attracting increasing research interest. A prerequisite for harvesting these functional properties in oxides requires successful introduction and control of dislocation density and arrangement without forming cracks, which is a great challenge due to their brittle nature. Here, we report a simple method to mechanically tailor the dislocation densities in single-crystal perovskite SrTiO3. By using a millimeter-sized Brinell indenter, dislocation densities from ∼1010 to ∼1013 m−2 are achieved by increasing the number of indenting cycles. Depending on tip radius and indenting load, large and crack-free plastic zones over hundreds of micrometers are created. The dislocation multiplication mechanisms are discussed, and the work hardening in the plastic zone is evaluated by micro-hardness measurement as a function of dislocation density. This simple approach opens many new opportunities in the area of dislocation-tuned functional and mechanical studies.

Typ des Eintrags: Artikel
Erschienen: 2022
Autor(en): Okafor, Chukwudalu ; Ding, Kuan ; Zhou, Xiandong ; Durst, Karsten ; Rödel, Jürgen ; Fang, Xufei
Art des Eintrags: Bibliographie
Titel: Mechanical tailoring of dislocation densities in SrTiO3 at room temperature
Sprache: Englisch
Publikationsjahr: 3 Februar 2022
Verlag: Wiley-Blackwell
Titel der Zeitschrift, Zeitung oder Schriftenreihe: Journal of the American Ceramic Society
Jahrgang/Volume einer Zeitschrift: 105
(Heft-)Nummer: 4
DOI: 10.1111/jace.18277
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Kurzbeschreibung (Abstract):

Dislocation-tuned functional properties such as electrical conductivity, thermal conductivity, and ferroelectric properties in oxides are attracting increasing research interest. A prerequisite for harvesting these functional properties in oxides requires successful introduction and control of dislocation density and arrangement without forming cracks, which is a great challenge due to their brittle nature. Here, we report a simple method to mechanically tailor the dislocation densities in single-crystal perovskite SrTiO3. By using a millimeter-sized Brinell indenter, dislocation densities from ∼1010 to ∼1013 m−2 are achieved by increasing the number of indenting cycles. Depending on tip radius and indenting load, large and crack-free plastic zones over hundreds of micrometers are created. The dislocation multiplication mechanisms are discussed, and the work hardening in the plastic zone is evaluated by micro-hardness measurement as a function of dislocation density. This simple approach opens many new opportunities in the area of dislocation-tuned functional and mechanical studies.

Freie Schlagworte: Cyclic loading, dislocations, hardness, strontium titanate
Fachbereich(e)/-gebiet(e): 11 Fachbereich Material- und Geowissenschaften
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Nichtmetallisch-Anorganische Werkstoffe
Hinterlegungsdatum: 04 Feb 2022 07:06
Letzte Änderung: 03 Jul 2024 02:55
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