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Investigation of residual stress in lead-free BNT-based ceramic/ceramic composites

Ayrikyan, A. ; Prach, Olena ; Khansur, N. H. ; Keller, S. ; Yasui, S. ; Itoh, M. ; Sakata, O. ; Durst, Karsten ; Webber, K. G. (2018)
Investigation of residual stress in lead-free BNT-based ceramic/ceramic composites.
In: Acta Materialia, 148
Artikel, Bibliographie

Kurzbeschreibung (Abstract)

Ceramic/ceramic composite structures have been proposed as a method for optimizing the electromechanical response of lead-free ferroelectrics. Co-sintering of ceramic composites, however, results in internal residual stresses as well as interdiffusion. In this investigation, the interaction between a nonergodic relaxor ferroelectric 0.93(Bi1/2Na1/2TiO3)-0.07BaTiO3 and an ergodic relaxor ferroelectric 0.94Bi1/2(Na0.78K0.22)1/2TiO3-0.06BiAlO3 in a multilayered composite structure is presented. The interaction between the two end members was analyzed both chemically and mechanically. The interdiffusion was characterized by EDX measurements and directly compared to the local mechanical properties as determined by nanoindentation. Vickers indentation was used to demonstrate the internal residual stresses through the indentation crack length anisotropy. Mechanical and chemical data are contrasted to a micro-XRD analysis, which reveals a change in the crystal structure of both end-members, most likely due to changes in the A-site elements as a result of interdiffusion.

Typ des Eintrags: Artikel
Erschienen: 2018
Autor(en): Ayrikyan, A. ; Prach, Olena ; Khansur, N. H. ; Keller, S. ; Yasui, S. ; Itoh, M. ; Sakata, O. ; Durst, Karsten ; Webber, K. G.
Art des Eintrags: Bibliographie
Titel: Investigation of residual stress in lead-free BNT-based ceramic/ceramic composites
Sprache: Englisch
Publikationsjahr: 2018
Verlag: Elsevier
Titel der Zeitschrift, Zeitung oder Schriftenreihe: Acta Materialia
Jahrgang/Volume einer Zeitschrift: 148
Kurzbeschreibung (Abstract):

Ceramic/ceramic composite structures have been proposed as a method for optimizing the electromechanical response of lead-free ferroelectrics. Co-sintering of ceramic composites, however, results in internal residual stresses as well as interdiffusion. In this investigation, the interaction between a nonergodic relaxor ferroelectric 0.93(Bi1/2Na1/2TiO3)-0.07BaTiO3 and an ergodic relaxor ferroelectric 0.94Bi1/2(Na0.78K0.22)1/2TiO3-0.06BiAlO3 in a multilayered composite structure is presented. The interaction between the two end members was analyzed both chemically and mechanically. The interdiffusion was characterized by EDX measurements and directly compared to the local mechanical properties as determined by nanoindentation. Vickers indentation was used to demonstrate the internal residual stresses through the indentation crack length anisotropy. Mechanical and chemical data are contrasted to a micro-XRD analysis, which reveals a change in the crystal structure of both end-members, most likely due to changes in the A-site elements as a result of interdiffusion.

Fachbereich(e)/-gebiet(e): 11 Fachbereich Material- und Geowissenschaften
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Physikalische Metallkunde
Hinterlegungsdatum: 18 Jul 2018 14:09
Letzte Änderung: 01 Feb 2019 11:46
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