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Deuterium REDOR: Principles and applications for distance measurements

Sack, I. ; Goldbourt, A. ; Vega, S. ; Buntkowsky, G. (1999)
Deuterium REDOR: Principles and applications for distance measurements.
In: Journal of Magnetic Resonance, 138 (1)
Article, Bibliographie

Abstract

The application of short composite pulse schemes (90(x)degrees-90(x)degrees-90(x)degrees and 90(x)degrees-180(x)degrees-90(x)degrees) to the rotational echo double-resonance (REDOR) spectroscopy of X-H-2 (X: spin 1/2 observed) systems with large deuterium quadrupolar interactions has been studied experimentally and theoretically and compared with simple 180 degrees pulse schemes. The basic properties of the composite pulses on the deuterium nuclei have been elucidated, using average Hamiltonian theory, and exact simulations of the experiments have been achieved by stepwise integration of the equation of motion of the density matrix, REDOR experiments were performed on N-15-H-2 in doubly labeled acetanilide and on C-13-H-2 in singly H-2-labeled acetanilide. The most efficient REDOR dephasing was observed when 90(x)degrees-180(x)degrees-90(x)degrees composite pulses were used. It is found that the dephasing due to simple 180 degrees deuterium pulses is about a factor of 2 less efficient than the dephasing due to the composite pulse sequences and thus the range of couplings observable by X-H-2 REDOR is enlarged toward weaker couplings, i.e., larger distances. From these experiments the H-2-N-15 dipolar coupling between the amino deuteron and the amino nitrogen and the H-2-C-13 dipolar couplings between the amino deuteron and the alpha and beta carbons have been elucidated and the corresponding distances have been determined, The distance data from REDOR are in good agreement with data from X-ray and neutron diffraction, showing the power of the method. (C) 1999 Academic Press.

Item Type: Article
Erschienen: 1999
Creators: Sack, I. ; Goldbourt, A. ; Vega, S. ; Buntkowsky, G.
Type of entry: Bibliographie
Title: Deuterium REDOR: Principles and applications for distance measurements
Language: English
Date: 1999
Journal or Publication Title: Journal of Magnetic Resonance
Volume of the journal: 138
Issue Number: 1
URL / URN: http://apps.webofknowledge.com/full_record.do?product=WOS&se...
Abstract:

The application of short composite pulse schemes (90(x)degrees-90(x)degrees-90(x)degrees and 90(x)degrees-180(x)degrees-90(x)degrees) to the rotational echo double-resonance (REDOR) spectroscopy of X-H-2 (X: spin 1/2 observed) systems with large deuterium quadrupolar interactions has been studied experimentally and theoretically and compared with simple 180 degrees pulse schemes. The basic properties of the composite pulses on the deuterium nuclei have been elucidated, using average Hamiltonian theory, and exact simulations of the experiments have been achieved by stepwise integration of the equation of motion of the density matrix, REDOR experiments were performed on N-15-H-2 in doubly labeled acetanilide and on C-13-H-2 in singly H-2-labeled acetanilide. The most efficient REDOR dephasing was observed when 90(x)degrees-180(x)degrees-90(x)degrees composite pulses were used. It is found that the dephasing due to simple 180 degrees deuterium pulses is about a factor of 2 less efficient than the dephasing due to the composite pulse sequences and thus the range of couplings observable by X-H-2 REDOR is enlarged toward weaker couplings, i.e., larger distances. From these experiments the H-2-N-15 dipolar coupling between the amino deuteron and the amino nitrogen and the H-2-C-13 dipolar couplings between the amino deuteron and the alpha and beta carbons have been elucidated and the corresponding distances have been determined, The distance data from REDOR are in good agreement with data from X-ray and neutron diffraction, showing the power of the method. (C) 1999 Academic Press.

Uncontrolled Keywords: h-2 redor composite pulses acetanilide c-13-h-2 distances n-15-h-2 distances double-resonance nmr echo double-resonance nuclear magnetic-resonance chemical-shift tensors rotational-echo glassy polycarbonate dipolar interactions composite pulses hydrogen-bonds local packing
Additional Information:

196HX Times Cited:30 Cited References Count:34

Divisions: 07 Department of Chemistry
07 Department of Chemistry > Eduard Zintl-Institut > Physical Chemistry
Date Deposited: 27 Oct 2014 20:48
Last Modified: 29 May 2019 11:55
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