Meštrić, Hrvoje ; Eichel, Rüdiger-A. ; Dinse, Klaus-Peter ; Ozarowski, Andrew ; Van Tol, Johan ; Brunel, Louis Claude (2004):
High-frequency electron paramagnetic resonance investigation of the Fe[sup 3+] impurity center in polycrystalline PbTiO[sub 3] in its ferroelectric phase.
In: Journal of Applied Physics, 96 (12), pp. 7440-1. ISSN 00218979,
[Article]
Abstract
The intrinsic iron(III) impurity center in polycrystalline lead titanate was investigated by means of high-frequency electron paramagnetic resonance spectroscopy in order to determine the local-environment sensitive fine-structure parameter D. At a spectrometer frequency of 190 GHz, a spectral analysis of a powder sample was unambiguously possible. The observed mean value D=+35.28 GHz can be rationalized if Fe3+ ions substitute for Ti4+ at the B site of the perovskite ABO3 lattice forming a directly coordinated FeTi′–VO⋅⋅ defect associate. A consistent fit of the multifrequency data necessitated the use of a distribution of the D values with a variance of about 1 GHz. This statistical distribution of values is probably related to more distant defects and vacancies.
| Item Type: | Article |
|---|---|
| Erschienen: | 2004 |
| Creators: | Meštrić, Hrvoje ; Eichel, Rüdiger-A. ; Dinse, Klaus-Peter ; Ozarowski, Andrew ; Van Tol, Johan ; Brunel, Louis Claude |
| Title: | High-frequency electron paramagnetic resonance investigation of the Fe[sup 3+] impurity center in polycrystalline PbTiO[sub 3] in its ferroelectric phase |
| Language: | English |
| Abstract: | The intrinsic iron(III) impurity center in polycrystalline lead titanate was investigated by means of high-frequency electron paramagnetic resonance spectroscopy in order to determine the local-environment sensitive fine-structure parameter D. At a spectrometer frequency of 190 GHz, a spectral analysis of a powder sample was unambiguously possible. The observed mean value D=+35.28 GHz can be rationalized if Fe3+ ions substitute for Ti4+ at the B site of the perovskite ABO3 lattice forming a directly coordinated FeTi′–VO⋅⋅ defect associate. A consistent fit of the multifrequency data necessitated the use of a distribution of the D values with a variance of about 1 GHz. This statistical distribution of values is probably related to more distant defects and vacancies. |
| Journal or Publication Title: | Journal of Applied Physics |
| Volume of the journal: | 96 |
| Issue Number: | 12 |
| Uncontrolled Keywords: | lead compounds, iron, powders, ferroelectric ceramics, EPR spectroscopy, vacancies (crystal), statistical distributions, spectral analysis |
| Divisions: | DFG-Collaborative Research Centres (incl. Transregio) > Collaborative Research Centres > CRC 595: Electrical fatigue > B - Characterisation > Subproject B1: EPR-Investigations of defects in ferroelectric ceramic material DFG-Collaborative Research Centres (incl. Transregio) > Collaborative Research Centres > CRC 595: Electrical fatigue > B - Characterisation DFG-Collaborative Research Centres (incl. Transregio) > Collaborative Research Centres > CRC 595: Electrical fatigue Zentrale Einrichtungen DFG-Collaborative Research Centres (incl. Transregio) > Collaborative Research Centres DFG-Collaborative Research Centres (incl. Transregio) |
| Date Deposited: | 08 Aug 2011 14:19 |
| URL / URN: | http://dx.doi.org/10.1063/1.1808477 |
| Additional Information: | SFB 595 B1 |
| Identification Number: | doi:10.1063/1.1808477 |
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