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Electric-field-induced volume change and room temperature phase stability of (Bi1/2Na1/2)TiO3-x mol. % BaTiO3 piezoceramics

Jo, Wook ; Rödel, Jürgen (2011):
Electric-field-induced volume change and room temperature phase stability of (Bi1/2Na1/2)TiO3-x mol. % BaTiO3 piezoceramics.
In: Applied Physics Letters, 99 (4), pp. 042901-1-042901-3. ISSN 00036951,
[Article]

Abstract

Phase stability of (1 − x) (Bi1/2Na1/2)TiO3-x BaTiO3 (0 ≤ x ≤ 0.15) under electric field was investigated by measuring volume changes during a bipolar poling cycle. The unique nature of field-dependent phase stability with three distinctive regions is revealed by comparative studies using commercial soft PZT and relaxor PLZT. For x ≤ 0.06 and x ≥ 0.13, similarly with PZT and PLZT, the axial strain expands with the contracting radial strain, but the former results in a remanent volume demonstrating an electric-field-induced phase transition. For 0.08 ≤ x ≤ 0.12, this field-induced phase transition is distinguished by negligible radial contractions implying polarization rotation. A “poling-induced” morphotropic phase boundary forms at x = 0.07.

Item Type: Article
Erschienen: 2011
Creators: Jo, Wook ; Rödel, Jürgen
Title: Electric-field-induced volume change and room temperature phase stability of (Bi1/2Na1/2)TiO3-x mol. % BaTiO3 piezoceramics
Language: English
Abstract:

Phase stability of (1 − x) (Bi1/2Na1/2)TiO3-x BaTiO3 (0 ≤ x ≤ 0.15) under electric field was investigated by measuring volume changes during a bipolar poling cycle. The unique nature of field-dependent phase stability with three distinctive regions is revealed by comparative studies using commercial soft PZT and relaxor PLZT. For x ≤ 0.06 and x ≥ 0.13, similarly with PZT and PLZT, the axial strain expands with the contracting radial strain, but the former results in a remanent volume demonstrating an electric-field-induced phase transition. For 0.08 ≤ x ≤ 0.12, this field-induced phase transition is distinguished by negligible radial contractions implying polarization rotation. A “poling-induced” morphotropic phase boundary forms at x = 0.07.

Journal or Publication Title: Applied Physics Letters
Volume of the journal: 99
Issue Number: 4
Uncontrolled Keywords: barium compounds, bismuth compounds, electric field effects, piezoceramics, sodium compounds
Divisions: 11 Department of Materials and Earth Sciences > Material Science > Nonmetallic-Inorganic Materials
DFG-Collaborative Research Centres (incl. Transregio) > Collaborative Research Centres > CRC 595: Electrical fatigue > A - Synthesis > Subproject A1: Manufacturing of ceramic, textured actuators with high strain
11 Department of Materials and Earth Sciences > Material Science
DFG-Collaborative Research Centres (incl. Transregio) > Collaborative Research Centres > CRC 595: Electrical fatigue > A - Synthesis
DFG-Collaborative Research Centres (incl. Transregio) > Collaborative Research Centres > CRC 595: Electrical fatigue
11 Department of Materials and Earth Sciences
Zentrale Einrichtungen
DFG-Collaborative Research Centres (incl. Transregio) > Collaborative Research Centres
DFG-Collaborative Research Centres (incl. Transregio)
Date Deposited: 26 Jul 2011 08:19
URL / URN: http://dx.doi.org/10.1063/1.3615675
Additional Information:

SFB 595 A1

Identification Number: doi:10.1063/1.3615675
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