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Synthesis and Characterization of Novel Oligoazulenes with Mixed Ethynyl and Butadiynyl Bridges

Elwahy, Ahmed H. M. ; Hafner, Klaus (2022):
Synthesis and Characterization of Novel Oligoazulenes with Mixed Ethynyl and Butadiynyl Bridges. (Publisher's Version)
In: European Journal of Organic Chemistry, 2006 (17), pp. 3910-3916. Wiley-VCH, e-ISSN 1099-0690,
DOI: 10.26083/tuprints-00022403,
[Article]

Abstract

The new oligoazulenes 10–14 with mixed ethynyl and butadiynyl bridges were synthesized by oxidative Eglinton coupling from the readily accessible ethynylazulenes 3, 4, 7, 9 and 15 as well as by Pd/Cu-catalyzed cross-coupling reactions with the appropriate iodoazulenes 5, 6 and 8.

Item Type: Article
Erschienen: 2022
Creators: Elwahy, Ahmed H. M. ; Hafner, Klaus
Origin: Secondary publication service
Status: Publisher's Version
Title: Synthesis and Characterization of Novel Oligoazulenes with Mixed Ethynyl and Butadiynyl Bridges
Language: English
Abstract:

The new oligoazulenes 10–14 with mixed ethynyl and butadiynyl bridges were synthesized by oxidative Eglinton coupling from the readily accessible ethynylazulenes 3, 4, 7, 9 and 15 as well as by Pd/Cu-catalyzed cross-coupling reactions with the appropriate iodoazulenes 5, 6 and 8.

Journal or Publication Title: European Journal of Organic Chemistry
Volume of the journal: 2006
Issue Number: 17
Place of Publication: Darmstadt
Publisher: Wiley-VCH
Uncontrolled Keywords: Ethynyl(iodo)azulenes / Oligoazulenes / Oxidative coupling / Cross-coupling
Divisions: 07 Department of Chemistry
07 Department of Chemistry > Organ Chemistry
Date Deposited: 23 Nov 2022 10:24
DOI: 10.26083/tuprints-00022403
URL / URN: https://tuprints.ulb.tu-darmstadt.de/22403
URN: urn:nbn:de:tuda-tuprints-224039
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