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Evaluation of mechanical properties and hydrophobicity of room‐temperature, moisture‐curable polysilazane coatings

Zhan, Ying ; Grottenmüller, Ralf ; Li, Wei ; Javaid, Farhan ; Riedel, Ralf (2021)
Evaluation of mechanical properties and hydrophobicity of room‐temperature, moisture‐curable polysilazane coatings.
In: Journal of Applied Polymer Science, 138 (21)
doi: 10.1002/app.50469
Artikel, Bibliographie

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Kurzbeschreibung (Abstract)

Polysilazane coatings have a broad need in real-life applications, which require low processing or working temperature. In this work, five commercially available polysilazanes have been spin-coated on polycarbonate substrates and cured in ambient environment and temperature to obtain transparent, crack-free, and dense films. The degree of crosslinking is found to have a significant impact on the hardness and Young's modulus of the polysilazane films but has a minor influence on the film thickness and hydrophobicity. Among all five polysilazane coatings, the inorganic perhydropolysilazane-based coating exhibits the largest hardness (2.05 +/- 0.01 GPa) and Young's modulus (10.76 +/- 0.03 GPa) after 7 days of curing, while the polyorganosilazane-derived films exhibit higher hydrophobicity. The molecular structure of polysilazanes plays a key role in mechanical properties and hydrophobicity of the associated films, as well as the adhesion of coatings to substrates, providing an intuitive and reliable way for selecting a suitable polysilazane coating material for a specific application.

Typ des Eintrags: Artikel
Erschienen: 2021
Autor(en): Zhan, Ying ; Grottenmüller, Ralf ; Li, Wei ; Javaid, Farhan ; Riedel, Ralf
Art des Eintrags: Bibliographie
Titel: Evaluation of mechanical properties and hydrophobicity of room‐temperature, moisture‐curable polysilazane coatings
Sprache: Englisch
Publikationsjahr: 14 Januar 2021
Verlag: Wiley
Titel der Zeitschrift, Zeitung oder Schriftenreihe: Journal of Applied Polymer Science
Jahrgang/Volume einer Zeitschrift: 138
(Heft-)Nummer: 21
DOI: 10.1002/app.50469
URL / URN: https://onlinelibrary.wiley.com/doi/10.1002/app.50469
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Kurzbeschreibung (Abstract):

Polysilazane coatings have a broad need in real-life applications, which require low processing or working temperature. In this work, five commercially available polysilazanes have been spin-coated on polycarbonate substrates and cured in ambient environment and temperature to obtain transparent, crack-free, and dense films. The degree of crosslinking is found to have a significant impact on the hardness and Young's modulus of the polysilazane films but has a minor influence on the film thickness and hydrophobicity. Among all five polysilazane coatings, the inorganic perhydropolysilazane-based coating exhibits the largest hardness (2.05 +/- 0.01 GPa) and Young's modulus (10.76 +/- 0.03 GPa) after 7 days of curing, while the polyorganosilazane-derived films exhibit higher hydrophobicity. The molecular structure of polysilazanes plays a key role in mechanical properties and hydrophobicity of the associated films, as well as the adhesion of coatings to substrates, providing an intuitive and reliable way for selecting a suitable polysilazane coating material for a specific application.

Freie Schlagworte: coatings, crosslinking, mechanical properties, structure‐property relationships, surfaces and interfaces
Fachbereich(e)/-gebiet(e): 11 Fachbereich Material- und Geowissenschaften
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Disperse Feststoffe
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Physikalische Metallkunde
Hinterlegungsdatum: 12 Mär 2021 07:20
Letzte Änderung: 06 Dez 2023 09:00
PPN:
Projekte: Merck KGaA, German Research Foundation (DFG), European Commission, Grant Number DU 424, ProjektDEAL
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