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Synthesis, morphology, thermal stability and magnetic properties of α ″ -Fe 16 N 2 nanoparticles obtained by hydrogen reduction of γ -Fe 2 O 3 and subsequent nitrogenation

Dirba, I. ; Schwöbel, C. A. ; Diop, L. V. B. ; Dürrschnabel, M. ; Molina-Luna, L. ; Hofmann, K. ; Komissinskiy, P. ; Kleebe, H.-J. ; Gutfleisch, O. (2017)
Synthesis, morphology, thermal stability and magnetic properties of α ″ -Fe 16 N 2 nanoparticles obtained by hydrogen reduction of γ -Fe 2 O 3 and subsequent nitrogenation.
In: Acta Materialia, 123
doi: 10.1016/j.actamat.2016.10.061
Artikel, Bibliographie

Kurzbeschreibung (Abstract)

Typical synthesis of α″-Fe16N2 nanoparticles involves reduction of iron oxides by hydrogen at elevated temperatures which is disadvantageous due to the particle coalescence. Here we report on a process for reduction of iron oxides at elevated pressures and show that by increasing hydrogen pressure from atmospheric to 53 MPa, it is possible to reduce the reaction temperature from 663 K down to 483 K, resulting in phase-pure α-Fe nanoparticles without noticeable particle growth. By subsequent nitrogenation in an ammonia flow, fine, 99% phase-pure α″-Fe16N2 nanoparticles could be synthesized. The reduction temperature and the respective particle size has a significant influence on the nitrogenation step. α″-Fe16N2 nanoparticles exhibit semi-hard magnetic properties with Ms(0) = 215 Am2 kg−1, μ0Hc = 0.22 T, TC = 634 K and exchange stiffness Ac = 6.84 pJ m−1, Aa,b = 7.53 pJ m−1. Synthesis conditions, microstructure, chemical composition and thermal stability of the nanoparticles are systematically studied and correlated with the observed magnetic properties.

Typ des Eintrags: Artikel
Erschienen: 2017
Autor(en): Dirba, I. ; Schwöbel, C. A. ; Diop, L. V. B. ; Dürrschnabel, M. ; Molina-Luna, L. ; Hofmann, K. ; Komissinskiy, P. ; Kleebe, H.-J. ; Gutfleisch, O.
Art des Eintrags: Bibliographie
Titel: Synthesis, morphology, thermal stability and magnetic properties of α ″ -Fe 16 N 2 nanoparticles obtained by hydrogen reduction of γ -Fe 2 O 3 and subsequent nitrogenation
Sprache: Englisch
Publikationsjahr: 15 Januar 2017
Verlag: Elsevier Science Publishing
Titel der Zeitschrift, Zeitung oder Schriftenreihe: Acta Materialia
Jahrgang/Volume einer Zeitschrift: 123
DOI: 10.1016/j.actamat.2016.10.061
URL / URN: https://doi.org/10.1016/j.actamat.2016.10.061
Kurzbeschreibung (Abstract):

Typical synthesis of α″-Fe16N2 nanoparticles involves reduction of iron oxides by hydrogen at elevated temperatures which is disadvantageous due to the particle coalescence. Here we report on a process for reduction of iron oxides at elevated pressures and show that by increasing hydrogen pressure from atmospheric to 53 MPa, it is possible to reduce the reaction temperature from 663 K down to 483 K, resulting in phase-pure α-Fe nanoparticles without noticeable particle growth. By subsequent nitrogenation in an ammonia flow, fine, 99% phase-pure α″-Fe16N2 nanoparticles could be synthesized. The reduction temperature and the respective particle size has a significant influence on the nitrogenation step. α″-Fe16N2 nanoparticles exhibit semi-hard magnetic properties with Ms(0) = 215 Am2 kg−1, μ0Hc = 0.22 T, TC = 634 K and exchange stiffness Ac = 6.84 pJ m−1, Aa,b = 7.53 pJ m−1. Synthesis conditions, microstructure, chemical composition and thermal stability of the nanoparticles are systematically studied and correlated with the observed magnetic properties.

Freie Schlagworte: Reduction, Nanoparticles, Permanent magnets, Fe16N2, Magnetic properties
Fachbereich(e)/-gebiet(e): 11 Fachbereich Material- und Geowissenschaften
11 Fachbereich Material- und Geowissenschaften > Geowissenschaften
11 Fachbereich Material- und Geowissenschaften > Geowissenschaften > Fachgebiet Geomaterialwissenschaft
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Dünne Schichten
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Funktionale Materialien
Hinterlegungsdatum: 11 Dez 2017 12:15
Letzte Änderung: 15 Sep 2021 08:08
PPN:
Sponsoren: I. D. thanks the BMBF for financial support within the project 03X3582., The authors thank the LOEWE project RESPONSE funded by the Ministry of Higher Education, Research and the Arts (HMWK) of the Hessen state., The transmission electron microscope used in this work was partially funded by the German Research Foundation (DFG/INST163/2951).
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