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Magnetization and stability study of a cobalt-ferrite-based ferrofluid

Kamali, Saeed ; Pouryazdan, Mohsen ; Ghafari, Mohammad ; Itou, Masayoshi ; Rahman, Masoud ; Stroeve, Pieter ; Hahn, Horst ; Sakurai, Yoshiharu (2016)
Magnetization and stability study of a cobalt-ferrite-based ferrofluid.
In: Journal of Magnetism and Magnetic Materials, 404
doi: 10.1016/j.jmmm.2015.12.007
Artikel, Bibliographie

Kurzbeschreibung (Abstract)

In this study the structural and magnetization properties of a CoFe2O4-based ferrofluid was investigated using x-ray diffraction (XRD), transmission electron microscopy (TEM), energy dispersive x-ray spectroscopy (EDS), Mossbauer spectroscopy, and magnetic Compton scattering (MCS) measurements. The XRD diagram indicates that the nanoparticles in the ferrofluid are inverse spinel and TEM graph shows that the ferrofluid consists of spherical nanoparticles with an average diameter of 18 +/- 1 nm, in good agreement with the size, 19.4 nm, extracted from line broadening of the XRD peaks. According to EDS measurements the composition of the nanoparticles is CoFe2O4. Mossbauer spectroscopy shows that the cation distributions are (Co0.38Fe0.62)[Co0.62Fe1.38]O-4. The MCS measurement, performed at 10 K, indicates that the magnetization of the nanoparticles is similar to magnetization of maghemite and magnetite. While the magnetization of the inverse spinels are in [111] direction, interestingly, the magnetization deduced from MCS is in [100] direction. The CoFe2O4-based ferrofluid is found to be stable at ambient conditions, which is important for applications. (C) 2015 Elsevier B.V. All rights reserved.

Typ des Eintrags: Artikel
Erschienen: 2016
Autor(en): Kamali, Saeed ; Pouryazdan, Mohsen ; Ghafari, Mohammad ; Itou, Masayoshi ; Rahman, Masoud ; Stroeve, Pieter ; Hahn, Horst ; Sakurai, Yoshiharu
Art des Eintrags: Bibliographie
Titel: Magnetization and stability study of a cobalt-ferrite-based ferrofluid
Sprache: Englisch
Publikationsjahr: 15 April 2016
Verlag: Elsevier Science BV, Netherlands
Titel der Zeitschrift, Zeitung oder Schriftenreihe: Journal of Magnetism and Magnetic Materials
Jahrgang/Volume einer Zeitschrift: 404
DOI: 10.1016/j.jmmm.2015.12.007
Kurzbeschreibung (Abstract):

In this study the structural and magnetization properties of a CoFe2O4-based ferrofluid was investigated using x-ray diffraction (XRD), transmission electron microscopy (TEM), energy dispersive x-ray spectroscopy (EDS), Mossbauer spectroscopy, and magnetic Compton scattering (MCS) measurements. The XRD diagram indicates that the nanoparticles in the ferrofluid are inverse spinel and TEM graph shows that the ferrofluid consists of spherical nanoparticles with an average diameter of 18 +/- 1 nm, in good agreement with the size, 19.4 nm, extracted from line broadening of the XRD peaks. According to EDS measurements the composition of the nanoparticles is CoFe2O4. Mossbauer spectroscopy shows that the cation distributions are (Co0.38Fe0.62)[Co0.62Fe1.38]O-4. The MCS measurement, performed at 10 K, indicates that the magnetization of the nanoparticles is similar to magnetization of maghemite and magnetite. While the magnetization of the inverse spinels are in [111] direction, interestingly, the magnetization deduced from MCS is in [100] direction. The CoFe2O4-based ferrofluid is found to be stable at ambient conditions, which is important for applications. (C) 2015 Elsevier B.V. All rights reserved.

Freie Schlagworte: Ferrofluid, Cobalt-ferrite, Nanoparticles, Mossbauer spectroscopy, Magnetic Compton scattering, Nano-magnetism
Fachbereich(e)/-gebiet(e): 11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Gemeinschaftslabor Nanomaterialien
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft
11 Fachbereich Material- und Geowissenschaften
Hinterlegungsdatum: 26 Jul 2017 12:21
Letzte Änderung: 26 Jul 2017 12:21
PPN:
Sponsoren: Saeed Kamali acknowledges Japan Society for the Promotion of Science for financial support.
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