Acosta, Matias ; Schmitt, Ljubomira A. ; Cazorla, Claudio ; Studer, Andrew ; Zintler, Alexander ; Glaum, Julia ; Kleebe, Hans-Joachim ; Donner, Wolfgang ; Hoffman, Mark ; Rödel, Jürgen ; Hinterstein, Manuel (2016)
Piezoelectricity and rotostriction through polar and non-polar coupled instabilities in bismuth-based piezoceramics.
In: Scientific Reports, 6 (1)
doi: 10.1038/srep28742
Artikel, Bibliographie
Kurzbeschreibung (Abstract)
Coupling of order parameters provides a means to tune functionality in advanced materials including multiferroics, superconductors, and ionic conductors. We demonstrate that the response of a frustrated ferroelectric state leads to coupling between order parameters under electric field depending on grain orientation. The strain of grains oriented along a specific crystallographic direction, 〈h00〉, is caused by converse piezoelectricity originating from a ferrodistortive tetragonal phase. For 〈hhh〉 oriented grains, the strain results from converse piezoelectricity and rotostriction, as indicated by an antiferrodistortive instability that promotes octahedral tilting in a rhombohedral phase. Both strain mechanisms combined lead to a colossal local strain of (2.4 ± 0.1) % and indicate coupling between oxygen octahedral tilting and polarization, here termed “rotopolarization”. These findings were confirmed with electromechanical experiments, in situ neutron diffraction, and in situ transmission electron microscopy in 0.75Bi1/2Na1/2TiO3-0.25SrTiO3. This work demonstrates that polar and non-polar instabilities can cooperate to provide colossal functional responses.
| Typ des Eintrags: | Artikel |
|---|---|
| Erschienen: | 2016 |
| Autor(en): | Acosta, Matias ; Schmitt, Ljubomira A. ; Cazorla, Claudio ; Studer, Andrew ; Zintler, Alexander ; Glaum, Julia ; Kleebe, Hans-Joachim ; Donner, Wolfgang ; Hoffman, Mark ; Rödel, Jürgen ; Hinterstein, Manuel |
| Art des Eintrags: | Bibliographie |
| Titel: | Piezoelectricity and rotostriction through polar and non-polar coupled instabilities in bismuth-based piezoceramics |
| Sprache: | Englisch |
| Publikationsjahr: | 2016 |
| Verlag: | Nature Research |
| Titel der Zeitschrift, Zeitung oder Schriftenreihe: | Scientific Reports |
| Jahrgang/Volume einer Zeitschrift: | 6 |
| (Heft-)Nummer: | 1 |
| DOI: | 10.1038/srep28742 |
| Kurzbeschreibung (Abstract): | Coupling of order parameters provides a means to tune functionality in advanced materials including multiferroics, superconductors, and ionic conductors. We demonstrate that the response of a frustrated ferroelectric state leads to coupling between order parameters under electric field depending on grain orientation. The strain of grains oriented along a specific crystallographic direction, 〈h00〉, is caused by converse piezoelectricity originating from a ferrodistortive tetragonal phase. For 〈hhh〉 oriented grains, the strain results from converse piezoelectricity and rotostriction, as indicated by an antiferrodistortive instability that promotes octahedral tilting in a rhombohedral phase. Both strain mechanisms combined lead to a colossal local strain of (2.4 ± 0.1) % and indicate coupling between oxygen octahedral tilting and polarization, here termed “rotopolarization”. These findings were confirmed with electromechanical experiments, in situ neutron diffraction, and in situ transmission electron microscopy in 0.75Bi1/2Na1/2TiO3-0.25SrTiO3. This work demonstrates that polar and non-polar instabilities can cooperate to provide colossal functional responses. |
| Fachbereich(e)/-gebiet(e): | 11 Fachbereich Material- und Geowissenschaften 11 Fachbereich Material- und Geowissenschaften > Geowissenschaften 11 Fachbereich Material- und Geowissenschaften > Geowissenschaften > Fachgebiet Geomaterialwissenschaft 11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft 11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Nichtmetallisch-Anorganische Werkstoffe 11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Strukturforschung |
| Hinterlegungsdatum: | 11 Jul 2017 11:41 |
| Letzte Änderung: | 13 Aug 2021 07:24 |
| PPN: | |
| Sponsoren: | The work and the in situ TEM experiments were supported by the Deutsche Forschungsgemeinschaft (DFG) Leibniz program under RO954/22-1, Emmy Noether Research Group HI1867/1-1 and SFB595., Further founds were obtained from the Bundesministerium fuer Bildung und Forschung (BMBF) (Grant No. 05K13VK1), the Feodor Lynen Research Fellowship Program of the Alexander von Humboldt Foundation., Further founds were obtained from the EU call H2020-MSCA-IF-2014 under grant number 655866 and the Australian Research Council under grant numbers DP150104649, DE120102644, DE150100750, and FT140100135. |
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