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Influence of external compressive stress on the ionic conductivity of melt-quenched lithium silicate (15Li2O-85SiO2) glass

Graczyk-Zajac, M. ; Vrankovic, D. ; Schader, F. H. ; Fernandes, H. R. ; Tulyaganov, D. U. (2017)
Influence of external compressive stress on the ionic conductivity of melt-quenched lithium silicate (15Li2O-85SiO2) glass.
In: Solid State Ionics, 302
doi: 10.1016/j.ssi.2016.11.024
Artikel, Bibliographie

Kurzbeschreibung (Abstract)

This paper reports measurements of the electrical resistances of bulk and milled amorphous lithium silicate (15Li2O-85SiO2) under uniaxial load at 200 °C. With imposed load up to 700 MPa, the resistance of the melt-quenched glass increases from 1.56 to 1.95 MΩ cm. This change is reversible, namely after releasing the load the initial electrical resistance is recovered. Milled and compacted glass consists of the bulk and particle contacts resistances. Both of them increase when the external compression up to 200 MPa. For the bulk element, when compression is released, the initial resistance is recovered, whereas the resistance changes within the particles contacts are irreversible.

Typ des Eintrags: Artikel
Erschienen: 2017
Autor(en): Graczyk-Zajac, M. ; Vrankovic, D. ; Schader, F. H. ; Fernandes, H. R. ; Tulyaganov, D. U.
Art des Eintrags: Bibliographie
Titel: Influence of external compressive stress on the ionic conductivity of melt-quenched lithium silicate (15Li2O-85SiO2) glass
Sprache: Englisch
Publikationsjahr: April 2017
Verlag: Elsevier
Titel der Zeitschrift, Zeitung oder Schriftenreihe: Solid State Ionics
Jahrgang/Volume einer Zeitschrift: 302
DOI: 10.1016/j.ssi.2016.11.024
Kurzbeschreibung (Abstract):

This paper reports measurements of the electrical resistances of bulk and milled amorphous lithium silicate (15Li2O-85SiO2) under uniaxial load at 200 °C. With imposed load up to 700 MPa, the resistance of the melt-quenched glass increases from 1.56 to 1.95 MΩ cm. This change is reversible, namely after releasing the load the initial electrical resistance is recovered. Milled and compacted glass consists of the bulk and particle contacts resistances. Both of them increase when the external compression up to 200 MPa. For the bulk element, when compression is released, the initial resistance is recovered, whereas the resistance changes within the particles contacts are irreversible.

Freie Schlagworte: Ionic conductivity, Compressive stress, Amorphous 15Li2O-85SiO2
Fachbereich(e)/-gebiet(e): 11 Fachbereich Material- und Geowissenschaften
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Disperse Feststoffe
Hinterlegungsdatum: 17 Mär 2017 09:25
Letzte Änderung: 24 Jan 2019 12:43
PPN:
Sponsoren: F.H.S. gratefully acknowledges financial support from the Deutsche Forschungsgemeinschaft under WE 4972/2.
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