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Hardening behavior and highly enhanced mechanical quality factor in(K0.5Na0.5)NbO3–based ceramics

Han, Hyoung-Su ; Koruza, Jurij ; Patterson, Eric A. ; Schultheiß, Jan ; Erdem, Emre ; Jo, Wook ; Lee, Jae-Shin ; Rödel, Jürgen (2017)
Hardening behavior and highly enhanced mechanical quality factor in(K0.5Na0.5)NbO3–based ceramics.
In: Journal of the European Ceramic Society, 37 (5)
doi: 10.1016/j.jeurceramsoc.2017.01.013
Artikel, Bibliographie

Kurzbeschreibung (Abstract)

This paper relates the microstructure, crystallographic structure, ferroelectric, and piezoelectric prop-erties of (K0.5Na0.5)NbO3(KNN) ceramics modified with 0.38 mol% K5.4Cu1.3Ta10O29(KCT) and differentamounts of CuO. Results revealed that the addition of KCT and CuO were effective in enhancing thesinterability of KNN. The internal bias field (Eib) increased from 0.3 kV/mm to 0.58 kV/mm at 0.5 mol%CuO–added KNN+KCT ceramics. The increase of Eibcorresponds very well with the observed increase ofthe mechanical quality factor (Qm) from 112 to 2665 for 0.5 mol% CuO. Besides, addition of 0.5 mol% CuOto KNN+KCT resulted in a large increase of the EPR signal, which is related to the increased amount Cu2+and a corresponding increase of the concentration of defect dipoles. This result is in good agreement withthe increased Eiband the resulting hardening behavior.

Typ des Eintrags: Artikel
Erschienen: 2017
Autor(en): Han, Hyoung-Su ; Koruza, Jurij ; Patterson, Eric A. ; Schultheiß, Jan ; Erdem, Emre ; Jo, Wook ; Lee, Jae-Shin ; Rödel, Jürgen
Art des Eintrags: Bibliographie
Titel: Hardening behavior and highly enhanced mechanical quality factor in(K0.5Na0.5)NbO3–based ceramics
Sprache: Englisch
Publikationsjahr: 20 Februar 2017
Verlag: Elsevier
Titel der Zeitschrift, Zeitung oder Schriftenreihe: Journal of the European Ceramic Society
Jahrgang/Volume einer Zeitschrift: 37
(Heft-)Nummer: 5
DOI: 10.1016/j.jeurceramsoc.2017.01.013
Kurzbeschreibung (Abstract):

This paper relates the microstructure, crystallographic structure, ferroelectric, and piezoelectric prop-erties of (K0.5Na0.5)NbO3(KNN) ceramics modified with 0.38 mol% K5.4Cu1.3Ta10O29(KCT) and differentamounts of CuO. Results revealed that the addition of KCT and CuO were effective in enhancing thesinterability of KNN. The internal bias field (Eib) increased from 0.3 kV/mm to 0.58 kV/mm at 0.5 mol%CuO–added KNN+KCT ceramics. The increase of Eibcorresponds very well with the observed increase ofthe mechanical quality factor (Qm) from 112 to 2665 for 0.5 mol% CuO. Besides, addition of 0.5 mol% CuOto KNN+KCT resulted in a large increase of the EPR signal, which is related to the increased amount Cu2+and a corresponding increase of the concentration of defect dipoles. This result is in good agreement withthe increased Eiband the resulting hardening behavior.

Freie Schlagworte: Lead-free Piezoelectric ceramics KNN Hardening effect Mechanical quality factor
Fachbereich(e)/-gebiet(e): 11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Nichtmetallisch-Anorganische Werkstoffe
11 Fachbereich Material- und Geowissenschaften
Hinterlegungsdatum: 21 Feb 2017 06:48
Letzte Änderung: 21 Feb 2017 06:48
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