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Phase transformation induced by electric field and mechanical stress in Mn-doped (Bi1/2Na1/2)TiO3-(Bi1/2K1/2)TiO3 ceramics

Ehara, Yoshitaka ; Novak, Nikola ; Ayrikyan, Azatuhi ; Geiger, Philipp T. ; Webber, Kyle G. (2016)
Phase transformation induced by electric field and mechanical stress in Mn-doped (Bi1/2Na1/2)TiO3-(Bi1/2K1/2)TiO3 ceramics.
In: Journal of Applied Physics, 120 (174103)
doi: 10.1063/1.4966614
Artikel, Bibliographie

Kurzbeschreibung (Abstract)

Electric-field- and stress-induced phase transformations were investigated in polycrystalline 0.5 mol. % Mn-doped (1�x)(Bi1/2Na1/2)TiO3-x(Bi1/2K1/2)TiO3 (x ¼ 0.1, 0.2). To characterize the effect of electric field and stress on the stability of the ferroelectric and relaxor states, polarizationand current density-electric field curves, as well as the stress-strain response as a function of temperature were characterized. Analogous to the observed electrical behavior, the macroscopic mechanical constitutive behavior showed a closed hysteresis at elevated temperatures, indicating a reversible stress-induced relaxor-to-ferroelectric transformation. The electrical and mechanical measurements were used to construct electric field–temperature and stress-temperature phase diagrams, which show similar characteristics. These data show that a mechanical compressive stress,similarly to an electric field, can induce long-range ferroelectric order in a relaxor ferroelectric.

Typ des Eintrags: Artikel
Erschienen: 2016
Autor(en): Ehara, Yoshitaka ; Novak, Nikola ; Ayrikyan, Azatuhi ; Geiger, Philipp T. ; Webber, Kyle G.
Art des Eintrags: Bibliographie
Titel: Phase transformation induced by electric field and mechanical stress in Mn-doped (Bi1/2Na1/2)TiO3-(Bi1/2K1/2)TiO3 ceramics
Sprache: Englisch
Publikationsjahr: 7 November 2016
Verlag: AIP Publishing
Titel der Zeitschrift, Zeitung oder Schriftenreihe: Journal of Applied Physics
Jahrgang/Volume einer Zeitschrift: 120
(Heft-)Nummer: 174103
DOI: 10.1063/1.4966614
Kurzbeschreibung (Abstract):

Electric-field- and stress-induced phase transformations were investigated in polycrystalline 0.5 mol. % Mn-doped (1�x)(Bi1/2Na1/2)TiO3-x(Bi1/2K1/2)TiO3 (x ¼ 0.1, 0.2). To characterize the effect of electric field and stress on the stability of the ferroelectric and relaxor states, polarizationand current density-electric field curves, as well as the stress-strain response as a function of temperature were characterized. Analogous to the observed electrical behavior, the macroscopic mechanical constitutive behavior showed a closed hysteresis at elevated temperatures, indicating a reversible stress-induced relaxor-to-ferroelectric transformation. The electrical and mechanical measurements were used to construct electric field–temperature and stress-temperature phase diagrams, which show similar characteristics. These data show that a mechanical compressive stress,similarly to an electric field, can induce long-range ferroelectric order in a relaxor ferroelectric.

Fachbereich(e)/-gebiet(e): 11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Nichtmetallisch-Anorganische Werkstoffe
11 Fachbereich Material- und Geowissenschaften
Hinterlegungsdatum: 15 Nov 2016 06:41
Letzte Änderung: 15 Nov 2016 06:41
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