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Phase transition behavior, dielectric and ferroelectric properties of (1 − x)(Bi0.5Na0.5)TiO3-xBa0.85Ca0.15Ti0.9Zr0.1O3 ceramics

Pu, Yongping ; Yao, Mouteng ; Liu, Hairui ; Frömling, Till (2016)
Phase transition behavior, dielectric and ferroelectric properties of (1 − x)(Bi0.5Na0.5)TiO3-xBa0.85Ca0.15Ti0.9Zr0.1O3 ceramics.
In: Journal of the European Ceramic Society, 36 (10)
doi: 10.1016/j.jeurceramsoc.2016.03.005
Artikel, Bibliographie

Kurzbeschreibung (Abstract)

(1 − x)(Bi0.5Na0.5)TiO3-xBa0.85Ca0.15Ti0.9Zr0.1O3 ceramics were prepared by solid state route and their phase structure and electric properties were investigated with the focus on optimizing properties for capacitor applications. There are two obvious maxima in the permittivity curves for x = 0.1–0.4 compositions. The first anomaly is suggested to be due to thermal evolution of LT-PNRs and the second one is attributed to the phase transition between the two types PNRs and the thermal evolution of HT-PNRs. The x = 0.3 sample has an operational temperature range from 87 ◦C to 310 ◦C. Most of the samples exhibit a dielectric thermal hysteresis. The x = 0.2–0.4 compositions exhibit a significant pinched P-E hysteresis loops. A large d33* of 427 pm/V was observed in 0.7BNT-0.3BCTZ composition. The x = 0.5–0.6 samples show a slim P-E hysteresis loop, and the sample with x = 0.5 exhibits high energy density of 0.6649 J/cm3 and energy storage efficiency of 83.17%, making it most suitable for application as high energy density capacitors.

Typ des Eintrags: Artikel
Erschienen: 2016
Autor(en): Pu, Yongping ; Yao, Mouteng ; Liu, Hairui ; Frömling, Till
Art des Eintrags: Bibliographie
Titel: Phase transition behavior, dielectric and ferroelectric properties of (1 − x)(Bi0.5Na0.5)TiO3-xBa0.85Ca0.15Ti0.9Zr0.1O3 ceramics
Sprache: Englisch
Publikationsjahr: 15 März 2016
Verlag: Elsevier
Titel der Zeitschrift, Zeitung oder Schriftenreihe: Journal of the European Ceramic Society
Jahrgang/Volume einer Zeitschrift: 36
(Heft-)Nummer: 10
DOI: 10.1016/j.jeurceramsoc.2016.03.005
Kurzbeschreibung (Abstract):

(1 − x)(Bi0.5Na0.5)TiO3-xBa0.85Ca0.15Ti0.9Zr0.1O3 ceramics were prepared by solid state route and their phase structure and electric properties were investigated with the focus on optimizing properties for capacitor applications. There are two obvious maxima in the permittivity curves for x = 0.1–0.4 compositions. The first anomaly is suggested to be due to thermal evolution of LT-PNRs and the second one is attributed to the phase transition between the two types PNRs and the thermal evolution of HT-PNRs. The x = 0.3 sample has an operational temperature range from 87 ◦C to 310 ◦C. Most of the samples exhibit a dielectric thermal hysteresis. The x = 0.2–0.4 compositions exhibit a significant pinched P-E hysteresis loops. A large d33* of 427 pm/V was observed in 0.7BNT-0.3BCTZ composition. The x = 0.5–0.6 samples show a slim P-E hysteresis loop, and the sample with x = 0.5 exhibits high energy density of 0.6649 J/cm3 and energy storage efficiency of 83.17%, making it most suitable for application as high energy density capacitors.

Freie Schlagworte: Solid state synthesis; Polar nanoregions; Relaxor behavior; Energy density; High temperature capacitor
Fachbereich(e)/-gebiet(e): 11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Nichtmetallisch-Anorganische Werkstoffe
11 Fachbereich Material- und Geowissenschaften
Hinterlegungsdatum: 27 Sep 2016 05:43
Letzte Änderung: 27 Sep 2016 05:43
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