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Influence of B-Site Disorder on the Properties of Unpoled Bi1/2Na1/2TiO3-0.06Ba(ZrxTi1-x)O3 Piezoceramics

Glaum, Julia ; Zakhozheva, M. ; Acosta, Matias ; Aksel, Elena ; Kleebe, Hans-Joachim ; Hoffman, Mark ; Schmitt, Ljubomira Ana (2016)
Influence of B-Site Disorder on the Properties of Unpoled Bi1/2Na1/2TiO3-0.06Ba(ZrxTi1-x)O3 Piezoceramics.
In: Journal of the American Ceramic Society, 99 (8)
doi: 10.1111/jace.14266
Artikel, Bibliographie

Kurzbeschreibung (Abstract)

The influence of B-site disorder on the dielectric, microstructural, and structural characteristics of unpoled, lead-free (Bi1/2Na1/2)TiO3-0.06Ba(ZrxTi1-x)O3 piezoelectric ceramics with x = 0.02, 0.10, and 0.15 was investigated. The low and medium doping level introduced a stabilization of polar nanoregions reflected in the shift of the dispersive permittivity anomalies to higher temperatures and the development of lamellar rhombohedral domains embedded in the prevalent tetragonal nanodomain matrix. For higher Zr level, the regions of lamellar domains remain, but the dielectric characteristics indicate a reduction in the previous stabilization effect. This behavior is rationalized by a reduction in the correlation length due to the increasing amount of nonpolar sample volume with increasing Zr addition.

Typ des Eintrags: Artikel
Erschienen: 2016
Autor(en): Glaum, Julia ; Zakhozheva, M. ; Acosta, Matias ; Aksel, Elena ; Kleebe, Hans-Joachim ; Hoffman, Mark ; Schmitt, Ljubomira Ana
Art des Eintrags: Bibliographie
Titel: Influence of B-Site Disorder on the Properties of Unpoled Bi1/2Na1/2TiO3-0.06Ba(ZrxTi1-x)O3 Piezoceramics
Sprache: Englisch
Publikationsjahr: 14 September 2016
Verlag: The American Ceramic Society
Titel der Zeitschrift, Zeitung oder Schriftenreihe: Journal of the American Ceramic Society
Jahrgang/Volume einer Zeitschrift: 99
(Heft-)Nummer: 8
DOI: 10.1111/jace.14266
Kurzbeschreibung (Abstract):

The influence of B-site disorder on the dielectric, microstructural, and structural characteristics of unpoled, lead-free (Bi1/2Na1/2)TiO3-0.06Ba(ZrxTi1-x)O3 piezoelectric ceramics with x = 0.02, 0.10, and 0.15 was investigated. The low and medium doping level introduced a stabilization of polar nanoregions reflected in the shift of the dispersive permittivity anomalies to higher temperatures and the development of lamellar rhombohedral domains embedded in the prevalent tetragonal nanodomain matrix. For higher Zr level, the regions of lamellar domains remain, but the dielectric characteristics indicate a reduction in the previous stabilization effect. This behavior is rationalized by a reduction in the correlation length due to the increasing amount of nonpolar sample volume with increasing Zr addition.

Freie Schlagworte: relaxors; core–shell structures; dielectric materials/ properties; domains; transmission electron microscopy
Fachbereich(e)/-gebiet(e): 11 Fachbereich Material- und Geowissenschaften
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Nichtmetallisch-Anorganische Werkstoffe
Hinterlegungsdatum: 15 Sep 2016 05:44
Letzte Änderung: 12 Aug 2021 13:37
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