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Laser ablation behavior of Cf/SiHfBCN ceramic matrix composites

Luan, Xingang ; Yuan, Jia ; Wang, Jianqiang ; Tian, Min ; Cheng, Laifei ; Ionescu, Emanuel ; Riedel, Ralf (2016)
Laser ablation behavior of Cf/SiHfBCN ceramic matrix composites.
In: Journal of the European Ceramic Society, 36 (15)
doi: 10.1016/j.jeurceramsoc.2016.04.010
Artikel, Bibliographie

Kurzbeschreibung (Abstract)

The behavior of Cf/SiHfBCN composites upon laser ablation was investigated. The evolution of microstructure and phase composition of the composite was studied by scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS). It is found that the ablation mechanism and the microstructure evolution are mainly dependent on the local temperature which directly relies on the distance from the laser spot and the thermal conduction of the carbon fibers. Three regions with different ablation behavior are identified. In the center region, bubble-like structures consisting of HfO2, and SiHfxOy-based layers, cover the ends of the carbon fibers which retain their original shape despite their corrosion. Sheets consisting of HfCxOy and SiO2 as well as porous HfO2 and liquid SiO2 are generated in the transition region. The carbon fibers are well protected from oxidation in the two regions. SiO2 is produced and suppresses the further oxidation of the matrix in the fringe region.

Typ des Eintrags: Artikel
Erschienen: 2016
Autor(en): Luan, Xingang ; Yuan, Jia ; Wang, Jianqiang ; Tian, Min ; Cheng, Laifei ; Ionescu, Emanuel ; Riedel, Ralf
Art des Eintrags: Bibliographie
Titel: Laser ablation behavior of Cf/SiHfBCN ceramic matrix composites
Sprache: Englisch
Publikationsjahr: November 2016
Verlag: Elsevier Science Publishing
Titel der Zeitschrift, Zeitung oder Schriftenreihe: Journal of the European Ceramic Society
Jahrgang/Volume einer Zeitschrift: 36
(Heft-)Nummer: 15
DOI: 10.1016/j.jeurceramsoc.2016.04.010
Kurzbeschreibung (Abstract):

The behavior of Cf/SiHfBCN composites upon laser ablation was investigated. The evolution of microstructure and phase composition of the composite was studied by scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS). It is found that the ablation mechanism and the microstructure evolution are mainly dependent on the local temperature which directly relies on the distance from the laser spot and the thermal conduction of the carbon fibers. Three regions with different ablation behavior are identified. In the center region, bubble-like structures consisting of HfO2, and SiHfxOy-based layers, cover the ends of the carbon fibers which retain their original shape despite their corrosion. Sheets consisting of HfCxOy and SiO2 as well as porous HfO2 and liquid SiO2 are generated in the transition region. The carbon fibers are well protected from oxidation in the two regions. SiO2 is produced and suppresses the further oxidation of the matrix in the fringe region.

Freie Schlagworte: Laser ablation, Ablation mechanism, Cf/SiHfBCN, UHT CMCs
Zusätzliche Informationen:

Preparation and Application of Ultra-high Temperature Ceramic Matrix Composites

Fachbereich(e)/-gebiet(e): 11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Disperse Feststoffe
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft
11 Fachbereich Material- und Geowissenschaften
Hinterlegungsdatum: 17 Aug 2016 08:33
Letzte Änderung: 17 Aug 2016 08:33
PPN:
Sponsoren: The work is supported by the fund of 111 Project (B08040), the State Key Laboratory of Solidification Processing in NWPU (No. 135-QP-2015)., The authors also acknowledge the financial supports from the project supported by State Key Laboratory of Powder Metallurgy, Central South University, Changsha, China and the project sponsored by SRF for ROCS, SEM., JY acknowledges financial support from China Scholarship Council (CSC) during his stay at TU Darmstadt., Financial support from the German Research Foundation (DFG, Bonn, Germany) is gratefully acknowledged.
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