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Copper (I) Oxide (Cu2O) based back contact for p-i-n CdTe solar cells

Türck, Johannes ; Nonnenmacher, Hermann-Josef ; Connor, Paula M. L. ; Siol, Sebastian ; Siepchen, Bastian ; Heimfarth, Jan Peter ; Klein, Andreas ; Jaegermann, Wolfram (2016)
Copper (I) Oxide (Cu2O) based back contact for p-i-n CdTe solar cells.
In: Progress in Photovoltaics: Research and Applications, 24
doi: 10.1002/pip.2782
Artikel, Bibliographie

Kurzbeschreibung (Abstract)

In this paper a promising solution for the notorious problem of manufacturing a stable low ohmic back contact of a CdTe thin film superstrate solar cell is presented without using elemental copper. Instead we have used a Cu2O layer inserted between the CdTe absorber and metal contact (Au). In contrast to the barrier free band alignment gained by using the transitivity rules, XPS measurements show a barrier in the valence band of the Cu2O layers directly after deposition, which results in a low performing JV curve. The contact can be improved by a short thermal treatment resulting in efficiencies superior to copper based contacts for standard CdS/CdTe hetero junction solar cells prepared on commercial glass/FTO substrates. By replacing the CdS window layer with a CdS:O buffer layer efficiencies of >15% could be achieved.

Typ des Eintrags: Artikel
Erschienen: 2016
Autor(en): Türck, Johannes ; Nonnenmacher, Hermann-Josef ; Connor, Paula M. L. ; Siol, Sebastian ; Siepchen, Bastian ; Heimfarth, Jan Peter ; Klein, Andreas ; Jaegermann, Wolfram
Art des Eintrags: Bibliographie
Titel: Copper (I) Oxide (Cu2O) based back contact for p-i-n CdTe solar cells
Sprache: Englisch
Publikationsjahr: 2016
Titel der Zeitschrift, Zeitung oder Schriftenreihe: Progress in Photovoltaics: Research and Applications
Jahrgang/Volume einer Zeitschrift: 24
DOI: 10.1002/pip.2782
Kurzbeschreibung (Abstract):

In this paper a promising solution for the notorious problem of manufacturing a stable low ohmic back contact of a CdTe thin film superstrate solar cell is presented without using elemental copper. Instead we have used a Cu2O layer inserted between the CdTe absorber and metal contact (Au). In contrast to the barrier free band alignment gained by using the transitivity rules, XPS measurements show a barrier in the valence band of the Cu2O layers directly after deposition, which results in a low performing JV curve. The contact can be improved by a short thermal treatment resulting in efficiencies superior to copper based contacts for standard CdS/CdTe hetero junction solar cells prepared on commercial glass/FTO substrates. By replacing the CdS window layer with a CdS:O buffer layer efficiencies of >15% could be achieved.

Fachbereich(e)/-gebiet(e): 11 Fachbereich Material- und Geowissenschaften
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Oberflächenforschung
Hinterlegungsdatum: 12 Mai 2016 13:33
Letzte Änderung: 28 Aug 2016 15:06
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