Veber, Philippe ; Benabdallah, Feres ; Liu, Hairui ; Buse, Gabriel ; Josse, Michael ; Maglione, Mario (2015)
Growth and Characterization of Lead-free
Piezoelectric Single Crystals.
In: Materials, 8 (11)
doi: 10.3390/ma8115436
Artikel, Bibliographie
Kurzbeschreibung (Abstract)
Lead-free piezoelectric materials attract more and more attention owing to the environmental toxicity of lead-containing materials. In this work, we review our first attempts of single crystal grown by the top-seeded solution growth method of BaTiO3 substituted with zirconium and calcium (BCTZ) and (K0.5Na0.5)NbO3 substituted with lithium, tantalum, and antimony (KNLSTN). The growth methodology is optimized in order to reach the best compositions where enhanced properties are expected. Chemical analysis and electrical characterizations are presented for both kinds of crystals. The compositionally-dependent electrical performance is investigated for a better understanding of the relationship between the composition and electrical properties. A cross-over from relaxor to ferroelectric state in BCTZ solid solution is evidenced similar to the one reported in ceramics. In KNLSTN single crystals, we observed a substantial evolution of the orthorhombic-to-tetragonal phase transition under minute composition changes.
| Typ des Eintrags: | Artikel |
|---|---|
| Erschienen: | 2015 |
| Autor(en): | Veber, Philippe ; Benabdallah, Feres ; Liu, Hairui ; Buse, Gabriel ; Josse, Michael ; Maglione, Mario |
| Art des Eintrags: | Bibliographie |
| Titel: | Growth and Characterization of Lead-free Piezoelectric Single Crystals |
| Sprache: | Englisch |
| Publikationsjahr: | 24 November 2015 |
| Verlag: | MDPI Publishing |
| Titel der Zeitschrift, Zeitung oder Schriftenreihe: | Materials |
| Jahrgang/Volume einer Zeitschrift: | 8 |
| (Heft-)Nummer: | 11 |
| DOI: | 10.3390/ma8115436 |
| URL / URN: | http://pubs.rsc.org/en/Content/ArticleLanding/2016/CE/C5CE02... |
| Kurzbeschreibung (Abstract): | Lead-free piezoelectric materials attract more and more attention owing to the environmental toxicity of lead-containing materials. In this work, we review our first attempts of single crystal grown by the top-seeded solution growth method of BaTiO3 substituted with zirconium and calcium (BCTZ) and (K0.5Na0.5)NbO3 substituted with lithium, tantalum, and antimony (KNLSTN). The growth methodology is optimized in order to reach the best compositions where enhanced properties are expected. Chemical analysis and electrical characterizations are presented for both kinds of crystals. The compositionally-dependent electrical performance is investigated for a better understanding of the relationship between the composition and electrical properties. A cross-over from relaxor to ferroelectric state in BCTZ solid solution is evidenced similar to the one reported in ceramics. In KNLSTN single crystals, we observed a substantial evolution of the orthorhombic-to-tetragonal phase transition under minute composition changes. |
| Freie Schlagworte: | crystal growth; lead-free materials; piezoelectrics |
| Fachbereich(e)/-gebiet(e): | 11 Fachbereich Material- und Geowissenschaften 11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft 11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Nichtmetallisch-Anorganische Werkstoffe |
| Hinterlegungsdatum: | 23 Mär 2016 13:00 |
| Letzte Änderung: | 23 Mär 2016 13:00 |
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