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On-line Raman spectroscopy of calcite and malachite during irradiation with swift heavy ions

Dedera, Sebastian ; Burchard, Michael ; Glasmacher, Ulrich A. ; Schöppner, Nicole ; Trautmann, Christina ; Severin, Daniel ; Romanenko, Anton ; Hubert, Christian (2015):
On-line Raman spectroscopy of calcite and malachite during irradiation with swift heavy ions.
In: Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, 365, pp. 564-568. Elsevier Science BV, Netherlands, ISSN 0168583X,
[Article]

Abstract

A new on-line Raman System, which was installed at the M3-beamline at the UNILAC, GSI Helmholtzzentrum fur Schwerionenforschung Darmstadt was used for first "in situ" spectroscopic measurements. Calcite and malachite samples were irradiated in steps between 1 x 10(9) and 1 x 10(12) ions/cm(2) with Au ions (calcite) and Xe ions (malachite) at an energy of 4.8 MeV/u. After irradiation, calcite revealed a new Raman band at 437 cm(-1) and change of the full width at half maximum for the 1087 cm(-1) Raman band. The Raman bands of malachite change significantly with increasing fluence. Up to a fluence of 7 x 10(10) ions/cm(2), all existing bands decrease in intensity. Between 8 x 10(10) and 1 x 10(11) ions/cm(2) a broad Cu2O band between 110 and 220 cm(-1) occurs, which superimposes the pre-existing Raman bands. Additionally, a new broad band between 1000 and 1750 cm(-1) is formed, which is interpreted as a carbon coating. In contrast to the Cu2O band, the carbon band vanished when further irradiating the-sample. The installations as well as first in situ measurements at room temperature are presented. (C) 2015 Elsevier B.V. All rights reserved.

Item Type: Article
Erschienen: 2015
Creators: Dedera, Sebastian ; Burchard, Michael ; Glasmacher, Ulrich A. ; Schöppner, Nicole ; Trautmann, Christina ; Severin, Daniel ; Romanenko, Anton ; Hubert, Christian
Title: On-line Raman spectroscopy of calcite and malachite during irradiation with swift heavy ions
Language: English
Abstract:

A new on-line Raman System, which was installed at the M3-beamline at the UNILAC, GSI Helmholtzzentrum fur Schwerionenforschung Darmstadt was used for first "in situ" spectroscopic measurements. Calcite and malachite samples were irradiated in steps between 1 x 10(9) and 1 x 10(12) ions/cm(2) with Au ions (calcite) and Xe ions (malachite) at an energy of 4.8 MeV/u. After irradiation, calcite revealed a new Raman band at 437 cm(-1) and change of the full width at half maximum for the 1087 cm(-1) Raman band. The Raman bands of malachite change significantly with increasing fluence. Up to a fluence of 7 x 10(10) ions/cm(2), all existing bands decrease in intensity. Between 8 x 10(10) and 1 x 10(11) ions/cm(2) a broad Cu2O band between 110 and 220 cm(-1) occurs, which superimposes the pre-existing Raman bands. Additionally, a new broad band between 1000 and 1750 cm(-1) is formed, which is interpreted as a carbon coating. In contrast to the Cu2O band, the carbon band vanished when further irradiating the-sample. The installations as well as first in situ measurements at room temperature are presented. (C) 2015 Elsevier B.V. All rights reserved.

Journal or Publication Title: Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms
Journal volume: 365
Publisher: Elsevier Science BV, Netherlands
Uncontrolled Keywords: Raman spectroscopy, Ion irradiation, Calcite, Malachite, GSI
Divisions: 11 Department of Materials and Earth Sciences > Material Science > Ion-Beam-Modified Materials
05 Department of Physics > Institute of Applied Physics
11 Department of Materials and Earth Sciences > Material Science
11 Department of Materials and Earth Sciences
05 Department of Physics
Date Deposited: 29 Feb 2016 13:14
Official URL: http://dx.doi.org/10.1016/j.nimb.2015.09.079
Identification Number: doi:10.1016/j.nimb.2015.09.079
Funders: This study is financed by the BMBF Verbundprojekt 05KK7VH1.
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