Čechová, Danica ; Svoboda, Ingrid ; Jomová, Klaudia ; Růžičková, Zdeňka ; Valko, Marián ; Moncol, Ján (2015)
Synthesis, crystal structures and properties of coordination polymers from copper(II) adipate.
In: Transition Metal Chemistry, 40 (8)
doi: 10.1007/s11243-015-9982-6
Artikel, Bibliographie
Kurzbeschreibung (Abstract)
The synthesis, crystal structures and spectroscopy of [{Cu(mu(2)-adip)(benzim)(2)(H2O)}(n)] (1), [{Cu(mu(2)-adip)(4-pyme)(2)(H2O)}(n)] (2), [{Cu(mu(3)-adip)(nia)(2)}(n)center dot nH(2)O] (3), [{Cu(mu(2)-adip)(pydca)(2)}(n)] (4) and [{Cu(mu(4)-adip)(mna)}(n)center dot nH(2)O] (5) (adip = adipate(2-) anion, benzim = benzimidazole, 4-pyme = 4-pyridylmethanol, nia = nicotinamide, pydca = 3,4-pyridinedicarboxamide, mna = N-methylnicotinamide) are reported. The complexes under study were characterized by electronic, IR and EPR spectroscopy, and single-crystal X-ray structure analysis. The complexes form one-dimensional or two-dimensional brick-wall like coordination polymers. The coordination environments around the copper atoms of complexes 1-3 and 5 are distorted tetragonal pyramidal. The copper atom in complex 4 has tetragonal-bipyramidal coordination. Four different coordination modes of adipate ligands in the studied copper(II) complexes were observed. The coordination polymers of the complexes are connected through hydrogen bonds into 2-D or 3-D supramolecular frameworks.
| Typ des Eintrags: | Artikel |
|---|---|
| Erschienen: | 2015 |
| Autor(en): | Čechová, Danica ; Svoboda, Ingrid ; Jomová, Klaudia ; Růžičková, Zdeňka ; Valko, Marián ; Moncol, Ján |
| Art des Eintrags: | Bibliographie |
| Titel: | Synthesis, crystal structures and properties of coordination polymers from copper(II) adipate |
| Sprache: | Englisch |
| Publikationsjahr: | November 2015 |
| Verlag: | Springer Netherlands |
| Titel der Zeitschrift, Zeitung oder Schriftenreihe: | Transition Metal Chemistry |
| Jahrgang/Volume einer Zeitschrift: | 40 |
| (Heft-)Nummer: | 8 |
| DOI: | 10.1007/s11243-015-9982-6 |
| Kurzbeschreibung (Abstract): | The synthesis, crystal structures and spectroscopy of [{Cu(mu(2)-adip)(benzim)(2)(H2O)}(n)] (1), [{Cu(mu(2)-adip)(4-pyme)(2)(H2O)}(n)] (2), [{Cu(mu(3)-adip)(nia)(2)}(n)center dot nH(2)O] (3), [{Cu(mu(2)-adip)(pydca)(2)}(n)] (4) and [{Cu(mu(4)-adip)(mna)}(n)center dot nH(2)O] (5) (adip = adipate(2-) anion, benzim = benzimidazole, 4-pyme = 4-pyridylmethanol, nia = nicotinamide, pydca = 3,4-pyridinedicarboxamide, mna = N-methylnicotinamide) are reported. The complexes under study were characterized by electronic, IR and EPR spectroscopy, and single-crystal X-ray structure analysis. The complexes form one-dimensional or two-dimensional brick-wall like coordination polymers. The coordination environments around the copper atoms of complexes 1-3 and 5 are distorted tetragonal pyramidal. The copper atom in complex 4 has tetragonal-bipyramidal coordination. Four different coordination modes of adipate ligands in the studied copper(II) complexes were observed. The coordination polymers of the complexes are connected through hydrogen bonds into 2-D or 3-D supramolecular frameworks. |
| Fachbereich(e)/-gebiet(e): | 11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Strukturforschung 11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft 11 Fachbereich Material- und Geowissenschaften |
| Hinterlegungsdatum: | 19 Jan 2016 12:00 |
| Letzte Änderung: | 19 Jan 2016 12:00 |
| PPN: | |
| Sponsoren: | We thank Slovak Research and Development Agency (APVV-14-0078), and Slovak Grant Agency (VEGA 1/0388/14 and 1/0765/14) for financial support. |
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