Schitco, Cristina ; Turdean-Ionescu, Claudia ; Bazarjani, Mahdi Seifollahi ; Tai, Cheuk-Wai ; Li, Duan ; Fasel, Claudia ; Donner, Wolfgang ; Shen, James ; Riedel, Ralf ; Gurlo, Aleksander ; Edén, Mattias (2016)
Silicon oxycarbonitrides synthesized by ammonia-assisted thermolysis route from polymers: A total X-ray scattering, solid-state NMR, and TEM structural study.
In: Journal of the European Ceramic Society, 36 (4)
doi: 10.1016/j.jeurceramsoc.2015.11.004
Artikel, Bibliographie
Kurzbeschreibung (Abstract)
Solid-state nuclear magnetic resonance (NMR) spectroscopy, total X-ray scattering with a pair distribution function (PDF) analysis, and transmission electron microscopy (TEM) were employed to explore the structures of microporous and non-porous ceramics synthesized by an NH3-assisted thermolysis from polymers. Polysiloxane (SPR-212a, Starfire® Systems) and polysilazane (HTT-1800, KiON Speciality Polymers) polymers form microporous silicon oxycarbonitride ceramics with accessible and tailored micropores. 29Si magic-angle-spinning NMR showed that the introduction of nitrogen leads to structures incorporating considerable amounts of SiN4 and SiO2N2 building blocks. The samples derived from a polycarbosilane (SMP-10, Starfire® Systems) remained non-porous: for such a C-rich and N-bearing phase, the NMR, TEM, and PDF results suggested a Si network exhibiting domains dominated by either Sisingle bondN or Sisingle bondC bonds. 13C NMR revealed primarily “carbidic” CSi4 environments in the C-rich phases, as well as the formation of an amorphous sp2-hybridized carbon phase; both are believed to be detrimental for the micropore formation.
| Typ des Eintrags: | Artikel |
|---|---|
| Erschienen: | 2016 |
| Autor(en): | Schitco, Cristina ; Turdean-Ionescu, Claudia ; Bazarjani, Mahdi Seifollahi ; Tai, Cheuk-Wai ; Li, Duan ; Fasel, Claudia ; Donner, Wolfgang ; Shen, James ; Riedel, Ralf ; Gurlo, Aleksander ; Edén, Mattias |
| Art des Eintrags: | Bibliographie |
| Titel: | Silicon oxycarbonitrides synthesized by ammonia-assisted thermolysis route from polymers: A total X-ray scattering, solid-state NMR, and TEM structural study |
| Sprache: | Englisch |
| Publikationsjahr: | März 2016 |
| Verlag: | Elsevier Science Publishing |
| Titel der Zeitschrift, Zeitung oder Schriftenreihe: | Journal of the European Ceramic Society |
| Jahrgang/Volume einer Zeitschrift: | 36 |
| (Heft-)Nummer: | 4 |
| DOI: | 10.1016/j.jeurceramsoc.2015.11.004 |
| Kurzbeschreibung (Abstract): | Solid-state nuclear magnetic resonance (NMR) spectroscopy, total X-ray scattering with a pair distribution function (PDF) analysis, and transmission electron microscopy (TEM) were employed to explore the structures of microporous and non-porous ceramics synthesized by an NH3-assisted thermolysis from polymers. Polysiloxane (SPR-212a, Starfire® Systems) and polysilazane (HTT-1800, KiON Speciality Polymers) polymers form microporous silicon oxycarbonitride ceramics with accessible and tailored micropores. 29Si magic-angle-spinning NMR showed that the introduction of nitrogen leads to structures incorporating considerable amounts of SiN4 and SiO2N2 building blocks. The samples derived from a polycarbosilane (SMP-10, Starfire® Systems) remained non-porous: for such a C-rich and N-bearing phase, the NMR, TEM, and PDF results suggested a Si network exhibiting domains dominated by either Sisingle bondN or Sisingle bondC bonds. 13C NMR revealed primarily “carbidic” CSi4 environments in the C-rich phases, as well as the formation of an amorphous sp2-hybridized carbon phase; both are believed to be detrimental for the micropore formation. |
| Freie Schlagworte: | Preceramic polymers, Microporous ceramics, Total X-ray scattering, 13C and 29Si MAS NMR, TEM |
| Fachbereich(e)/-gebiet(e): | 11 Fachbereich Material- und Geowissenschaften 11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft 11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Disperse Feststoffe 11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Strukturforschung |
| Hinterlegungsdatum: | 08 Jan 2016 09:08 |
| Letzte Änderung: | 30 Jan 2019 10:54 |
| PPN: | |
| Sponsoren: | M.E. acknowledges funding from the Faculty of Sciences at Stockholm University and NMR equipment Grants from the Swedish Research Council, and the Knut and Alice Wallenberg Foundation., C.T.-I. was supported by a postdoctoral grant from the Carl Trygger Foundation., The Knut and Alice Wallenberg (KAW) Foundation is acknowledged for providing the electron microscopy facilities and financial support to C.W.T. under the project 3DEM-NATUR., The European Union Seventh Framework Programme (FP7/2007-2013) under grant agreement no 264873 (FUNEA—Functional Nitrides for Energy Applications) is acknowledged. |
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