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Electric-field-temperature phase diagram of Mn-doped Bi0.5(Na0.9K0.1)0.5TiO3 ceramics

Ehara, Yoshitaka ; Novak, Nikola ; Shintaro, Yasui ; Itoh, Mitsuru ; Webber, Kyle G. (2015)
Electric-field-temperature phase diagram of Mn-doped Bi0.5(Na0.9K0.1)0.5TiO3 ceramics.
In: Applied Physics Letters, 107
doi: 10.1063/1.4938759
Artikel, Bibliographie

Kurzbeschreibung (Abstract)

An electric field–temperature (E-T) phase diagram for a lead-free 0.5 mol. % Mn-doped Bi(Na0.1K0.9)TiO3 ceramics was investigated. The x-ray diffraction, dielectric and polarization measurements revealed relaxor behavior and were used to characterize the stability regions of the non-ergodic relaxor, ergodic relaxor and electric field induced ferroelectric states. As indicated by the polarization–current density profiles, transformation between two electric fields, induced ferroelectric states with opposite polarization direction arise via a two-step process through an intermediate relaxor state. Interplay between the ferroelectric state conversion and intermediate relaxor state is governed by the dynamics of polarization relaxation. The presented E-T phase diagram revealed the effects of the applied electric field and temperature on stability regions. This is of special interest since the Bi0.5(Na0.1K0.9)0.5TiO3 ceramics were proposed as a potential piezoceramic material.

Typ des Eintrags: Artikel
Erschienen: 2015
Autor(en): Ehara, Yoshitaka ; Novak, Nikola ; Shintaro, Yasui ; Itoh, Mitsuru ; Webber, Kyle G.
Art des Eintrags: Bibliographie
Titel: Electric-field-temperature phase diagram of Mn-doped Bi0.5(Na0.9K0.1)0.5TiO3 ceramics
Sprache: Englisch
Publikationsjahr: 28 Dezember 2015
Titel der Zeitschrift, Zeitung oder Schriftenreihe: Applied Physics Letters
Jahrgang/Volume einer Zeitschrift: 107
DOI: 10.1063/1.4938759
Kurzbeschreibung (Abstract):

An electric field–temperature (E-T) phase diagram for a lead-free 0.5 mol. % Mn-doped Bi(Na0.1K0.9)TiO3 ceramics was investigated. The x-ray diffraction, dielectric and polarization measurements revealed relaxor behavior and were used to characterize the stability regions of the non-ergodic relaxor, ergodic relaxor and electric field induced ferroelectric states. As indicated by the polarization–current density profiles, transformation between two electric fields, induced ferroelectric states with opposite polarization direction arise via a two-step process through an intermediate relaxor state. Interplay between the ferroelectric state conversion and intermediate relaxor state is governed by the dynamics of polarization relaxation. The presented E-T phase diagram revealed the effects of the applied electric field and temperature on stability regions. This is of special interest since the Bi0.5(Na0.1K0.9)0.5TiO3 ceramics were proposed as a potential piezoceramic material.

Fachbereich(e)/-gebiet(e): 11 Fachbereich Material- und Geowissenschaften
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Nichtmetallisch-Anorganische Werkstoffe
Hinterlegungsdatum: 04 Jan 2016 16:31
Letzte Änderung: 04 Jan 2016 16:31
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