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Enhancing Electromechanical Properties of Lead-Free Ferroelectrics With Bilayer Ceramic/Ceramic Composites

Ayrikyan, Azatuhi ; Rojas, Virginia ; Molina-Luna, Leopoldo ; Acosta, Matias ; Koruza, Jurij ; Webber, Kyle G. (2015)
Enhancing Electromechanical Properties of Lead-Free Ferroelectrics With Bilayer Ceramic/Ceramic Composites.
In: IEEE Transactions on Ultrasonics, Ferroelectrics and Frequency Control, 62 (6)
doi: 10.1109/TUFFC.2014.006673
Artikel, Bibliographie

Kurzbeschreibung (Abstract)

The macroscopic electromechanical behavior of lead-free bilayer composites was characterized at room temperature. One layer consisted of a nonergodic relaxor,(Bi1/2 1 Na /2)TiO3–7 , BaTiO3 with an electric-field-induced longrange ferroelectric order, whereas the other is understood to be an ergodic relaxor [(Bi N 1/2 1 a ) /2 TiO3–25SrTiO3] that undergoes a reversible electric-field-induced macroscopic nonpolar-to-polar transition. Microstructural evidence of a bilayer with low diffusion between the two components is also demonstrated. By taking advantage of the different macroscopic strain– and polarization–electric-field responses of the two constituents, internal mechanical and electrical fields can be developed that enhance the unipolar strain over that expected by a rule of mixtures approximation, thereby improving the properties needed for application of such materials to actuator systems. It is possible through further tailoring of the volume fractions and macroscopic properties of the constituents to optimize the electromechanical properties of multilayer lead-free ferroelectrics.

Typ des Eintrags: Artikel
Erschienen: 2015
Autor(en): Ayrikyan, Azatuhi ; Rojas, Virginia ; Molina-Luna, Leopoldo ; Acosta, Matias ; Koruza, Jurij ; Webber, Kyle G.
Art des Eintrags: Bibliographie
Titel: Enhancing Electromechanical Properties of Lead-Free Ferroelectrics With Bilayer Ceramic/Ceramic Composites
Sprache: Englisch
Publikationsjahr: 3 Februar 2015
Verlag: IEEE
Titel der Zeitschrift, Zeitung oder Schriftenreihe: IEEE Transactions on Ultrasonics, Ferroelectrics and Frequency Control
Jahrgang/Volume einer Zeitschrift: 62
(Heft-)Nummer: 6
DOI: 10.1109/TUFFC.2014.006673
Kurzbeschreibung (Abstract):

The macroscopic electromechanical behavior of lead-free bilayer composites was characterized at room temperature. One layer consisted of a nonergodic relaxor,(Bi1/2 1 Na /2)TiO3–7 , BaTiO3 with an electric-field-induced longrange ferroelectric order, whereas the other is understood to be an ergodic relaxor [(Bi N 1/2 1 a ) /2 TiO3–25SrTiO3] that undergoes a reversible electric-field-induced macroscopic nonpolar-to-polar transition. Microstructural evidence of a bilayer with low diffusion between the two components is also demonstrated. By taking advantage of the different macroscopic strain– and polarization–electric-field responses of the two constituents, internal mechanical and electrical fields can be developed that enhance the unipolar strain over that expected by a rule of mixtures approximation, thereby improving the properties needed for application of such materials to actuator systems. It is possible through further tailoring of the volume fractions and macroscopic properties of the constituents to optimize the electromechanical properties of multilayer lead-free ferroelectrics.

Fachbereich(e)/-gebiet(e): 11 Fachbereich Material- und Geowissenschaften
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Nichtmetallisch-Anorganische Werkstoffe
Hinterlegungsdatum: 03 Nov 2015 10:19
Letzte Änderung: 08 Dez 2015 16:16
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