Mikhailova, D. ; Engel, J. M. ; Schmidt, M. ; Tsirlin, A. A. ; Ehrenberg, H. (2015):
Copper(II) perrhenate Cu(C3H7OH)2(ReO4)2: Synthesis from isopropanol and CuReO4, structure and properties.
In: Journal of Solid State Chemistry, 232, pp. 264-269. Elsevier Science Publishing, ISSN 00224596,
[Article]
Abstract
The crystal structure of Cu+Re7+O4 is capable of a quasi-reversible incorporation of C3H7OH molecules. A room-temperature reaction between CuReO4 and C3H7OH under oxidizing conditions leads to the formation of a novel metal-organic hybrid compound Cu2+(C3H7OH)2(ReO4)2. Upon heating under reducing conditions, this compound transforms back into CuReO4, albeit with ReO2 and metallic Cu as by-products. The crystal structure of Cu(C3H7OH)2(ReO4)2 solved from single-crystal X-ray diffraction (Pbca, a=10.005(3) Å, b=7.833(2) Å, and c=19.180(5) Å) reveals layers of corner-sharing CuO6-octahedra and ReO4-tetrahedra, whereas isopropyl groups are attached to both sides of these layers, thus providing additional connections within the layers through hydrogen bonds. Cu(C3H7OH)2(ReO4)2 is paramagnetic down to 4 K because the spatial arrangement of the Cu2+ half-filled orbitals prevents magnetic superexchange. The paramagnetic effective moment of 2.0(1) μB is slightly above the spin-only value and typical for Cu2+ ions.
| Item Type: | Article |
|---|---|
| Erschienen: | 2015 |
| Creators: | Mikhailova, D. ; Engel, J. M. ; Schmidt, M. ; Tsirlin, A. A. ; Ehrenberg, H. |
| Title: | Copper(II) perrhenate Cu(C3H7OH)2(ReO4)2: Synthesis from isopropanol and CuReO4, structure and properties |
| Language: | English |
| Abstract: | The crystal structure of Cu+Re7+O4 is capable of a quasi-reversible incorporation of C3H7OH molecules. A room-temperature reaction between CuReO4 and C3H7OH under oxidizing conditions leads to the formation of a novel metal-organic hybrid compound Cu2+(C3H7OH)2(ReO4)2. Upon heating under reducing conditions, this compound transforms back into CuReO4, albeit with ReO2 and metallic Cu as by-products. The crystal structure of Cu(C3H7OH)2(ReO4)2 solved from single-crystal X-ray diffraction (Pbca, a=10.005(3) Å, b=7.833(2) Å, and c=19.180(5) Å) reveals layers of corner-sharing CuO6-octahedra and ReO4-tetrahedra, whereas isopropyl groups are attached to both sides of these layers, thus providing additional connections within the layers through hydrogen bonds. Cu(C3H7OH)2(ReO4)2 is paramagnetic down to 4 K because the spatial arrangement of the Cu2+ half-filled orbitals prevents magnetic superexchange. The paramagnetic effective moment of 2.0(1) μB is slightly above the spin-only value and typical for Cu2+ ions. |
| Journal or Publication Title: | Journal of Solid State Chemistry |
| Journal volume: | 232 |
| Publisher: | Elsevier Science Publishing |
| Uncontrolled Keywords: | Metal-organic framework, Jahn–Teller distortion of CuO6 octahedra, Hydrogen bonds |
| Divisions: | 11 Department of Materials and Earth Sciences > Material Science > Structure Research 11 Department of Materials and Earth Sciences > Material Science 11 Department of Materials and Earth Sciences |
| Date Deposited: | 29 Oct 2015 09:49 |
| Official URL: | http://dx.doi.org/10.1016/j.jssc.2015.08.042 |
| Identification Number: | doi:10.1016/j.jssc.2015.08.042 |
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