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Increased magnetic moment induced by lattice expansion from α-Fe to α′-Fe8N

Dirba, Imants ; Komissinskiy, Philipp ; Gutfleisch, Oliver ; Alff, Lambert (2015)
Increased magnetic moment induced by lattice expansion from α-Fe to α′-Fe8N.
In: Journal of Applied Physics, 117 (17)
doi: 10.1063/1.4919601
Artikel, Bibliographie

Kurzbeschreibung (Abstract)

Buffer-free and epitaxial α-Fe and α' -Fe8N x thin films have been grown by RF magnetron sputtering onto MgO (100) substrates. The film thicknesses were determined with high accuracy by evaluating the Kiessig fringes of X-ray reflectometry measurements allowing a precise volume estimation. A gradual increase of the nitrogen content in the plasma led to an expansion of the iron bcc unit cell along the [001] direction resulting finally in a tetragonal distortion of about 10% corresponding to the formation of α' -Fe8N. The α-Fe lattice expansion was accompanied by an increase in magnetic moment to 2.61 ± 0.06μ B per Fe atom and a considerable increase in anisotropy. These experiments show that—without requiring any additional ordering of the nitrogen atoms—the lattice expansion of α-Fe itself is the origin of the increased magnetic moment in α' -Fe8N.

Typ des Eintrags: Artikel
Erschienen: 2015
Autor(en): Dirba, Imants ; Komissinskiy, Philipp ; Gutfleisch, Oliver ; Alff, Lambert
Art des Eintrags: Bibliographie
Titel: Increased magnetic moment induced by lattice expansion from α-Fe to α′-Fe8N
Sprache: Englisch
Publikationsjahr: 7 Mai 2015
Verlag: AIP Publishing
Titel der Zeitschrift, Zeitung oder Schriftenreihe: Journal of Applied Physics
Jahrgang/Volume einer Zeitschrift: 117
(Heft-)Nummer: 17
DOI: 10.1063/1.4919601
Kurzbeschreibung (Abstract):

Buffer-free and epitaxial α-Fe and α' -Fe8N x thin films have been grown by RF magnetron sputtering onto MgO (100) substrates. The film thicknesses were determined with high accuracy by evaluating the Kiessig fringes of X-ray reflectometry measurements allowing a precise volume estimation. A gradual increase of the nitrogen content in the plasma led to an expansion of the iron bcc unit cell along the [001] direction resulting finally in a tetragonal distortion of about 10% corresponding to the formation of α' -Fe8N. The α-Fe lattice expansion was accompanied by an increase in magnetic moment to 2.61 ± 0.06μ B per Fe atom and a considerable increase in anisotropy. These experiments show that—without requiring any additional ordering of the nitrogen atoms—the lattice expansion of α-Fe itself is the origin of the increased magnetic moment in α' -Fe8N.

Fachbereich(e)/-gebiet(e): 11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Dünne Schichten
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Funktionale Materialien
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft
11 Fachbereich Material- und Geowissenschaften
Hinterlegungsdatum: 02 Jul 2015 12:34
Letzte Änderung: 02 Jul 2015 12:34
PPN:
Sponsoren: I.D. thanks the BMBF for the financial support within the Project No. 03X3582., The authors thank the LOEWE project RESPONSE funded by the Ministry of Higher Education, Research and the Arts (HMWK) of the Hessen state.
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