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Methods to quantify groundwater pollution by airborne organic compounds and heavy metals

Schiedek, Thomas ; Hinderer, Matthias (2003)
Methods to quantify groundwater pollution by airborne organic compounds and heavy metals.
In: Mitteilungshefte des IGW, (3)
Artikel, Bibliographie

Kurzbeschreibung (Abstract)

Groundwater pollution due atmospheric deposition was investigated applying a mass balance concept at the catchment scale. A simple mass balance (input/output) was used to quantify overall natural attenuation of heavy metals (Zn, Cu, Ni, Cu, Pb, and Cd) and phthalates (DMP, DBP and DEHP) in two forested catchments in SW Germany (Seebach and Denzenberg valley). Decreasing concentrations from rainwater to groundwater, sorption rates of mostly more than 60% comparing input and output fluxes and preferential accumulation in the upper soil horizon confirmed the atmospheric origin of the heavy metals and phthalates investigated as well as the role of soils as a major sink for these pollutants. Sorption under equilibrium conditions would lead to lower groundwater concentrations than monitored, implying an additional non-equilibrium transport of the pollutants through the unsaturated zone by preferential flow. We recommend catchment area studies to assess the long-term risk of groundwater pollution due to diffusive atmospheric deposition of contaminants with high persistence.

Typ des Eintrags: Artikel
Erschienen: 2003
Autor(en): Schiedek, Thomas ; Hinderer, Matthias
Art des Eintrags: Bibliographie
Titel: Methods to quantify groundwater pollution by airborne organic compounds and heavy metals
Sprache: Englisch
Publikationsjahr: Januar 2003
Titel der Zeitschrift, Zeitung oder Schriftenreihe: Mitteilungshefte des IGW
(Heft-)Nummer: 3
Zugehörige Links:
Kurzbeschreibung (Abstract):

Groundwater pollution due atmospheric deposition was investigated applying a mass balance concept at the catchment scale. A simple mass balance (input/output) was used to quantify overall natural attenuation of heavy metals (Zn, Cu, Ni, Cu, Pb, and Cd) and phthalates (DMP, DBP and DEHP) in two forested catchments in SW Germany (Seebach and Denzenberg valley). Decreasing concentrations from rainwater to groundwater, sorption rates of mostly more than 60% comparing input and output fluxes and preferential accumulation in the upper soil horizon confirmed the atmospheric origin of the heavy metals and phthalates investigated as well as the role of soils as a major sink for these pollutants. Sorption under equilibrium conditions would lead to lower groundwater concentrations than monitored, implying an additional non-equilibrium transport of the pollutants through the unsaturated zone by preferential flow. We recommend catchment area studies to assess the long-term risk of groundwater pollution due to diffusive atmospheric deposition of contaminants with high persistence.

Zusätzliche Informationen:

Issue 3: Diffuse Input of Chemicals into Soil and Groundwater-Assessment & Management; IGW Workshop 2003

Fachbereich(e)/-gebiet(e): 11 Fachbereich Material- und Geowissenschaften
11 Fachbereich Material- und Geowissenschaften > Geowissenschaften
11 Fachbereich Material- und Geowissenschaften > Geowissenschaften > Fachgebiet Angewandte Sedimentgeologie
Hinterlegungsdatum: 22 Jun 2015 06:59
Letzte Änderung: 23 Nov 2020 15:41
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