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Oxidation Behavior of Binary Aluminium-Rich Fe–Al Alloys with a Fine-Scaled, Lamellar Microstructure

Scherf, A. ; Janda, D. ; Baghaie Yazdi, M. ; Li, X. ; Stein, F. ; Heilmaier, M. (2015)
Oxidation Behavior of Binary Aluminium-Rich Fe–Al Alloys with a Fine-Scaled, Lamellar Microstructure.
In: Oxidation of Metals
doi: 10.1007/s11085-015-9535-6
Artikel, Bibliographie

Kurzbeschreibung (Abstract)

The oxidation behavior of binary Fe–Al alloys with an aluminum content between 58 and 64 at.% was studied by isothermal and cyclic oxidation experiments in a temperature range of 900–1000 °C. The parabolic rate constants were determined to be comparable to those of B2-ordered Fe–48Al. All investigated alloys exhibited a fine-scaled, lamellar microstructure (<300 nm lamellar spacing), which was a result of the eutectoid decomposition of the high-temperature phase Fe5Al8 into FeAl and FeAl2. None of these two phases showed a preferential oxidation. At 900 °C θ-Al2O3 formed, whereas at 1000 °C a transformation of the initially formed θ-Al2O3 to the slower growing and passivating α-Al2O3 was confirmed by grazing incidence X-ray diffraction measurements.

Typ des Eintrags: Artikel
Erschienen: 2015
Autor(en): Scherf, A. ; Janda, D. ; Baghaie Yazdi, M. ; Li, X. ; Stein, F. ; Heilmaier, M.
Art des Eintrags: Bibliographie
Titel: Oxidation Behavior of Binary Aluminium-Rich Fe–Al Alloys with a Fine-Scaled, Lamellar Microstructure
Sprache: Englisch
Publikationsjahr: 2015
Verlag: Springer US
Titel der Zeitschrift, Zeitung oder Schriftenreihe: Oxidation of Metals
DOI: 10.1007/s11085-015-9535-6
Kurzbeschreibung (Abstract):

The oxidation behavior of binary Fe–Al alloys with an aluminum content between 58 and 64 at.% was studied by isothermal and cyclic oxidation experiments in a temperature range of 900–1000 °C. The parabolic rate constants were determined to be comparable to those of B2-ordered Fe–48Al. All investigated alloys exhibited a fine-scaled, lamellar microstructure (<300 nm lamellar spacing), which was a result of the eutectoid decomposition of the high-temperature phase Fe5Al8 into FeAl and FeAl2. None of these two phases showed a preferential oxidation. At 900 °C θ-Al2O3 formed, whereas at 1000 °C a transformation of the initially formed θ-Al2O3 to the slower growing and passivating α-Al2O3 was confirmed by grazing incidence X-ray diffraction measurements.

Freie Schlagworte: FeAl, FeAl2, Oxidation, Microstructure
Fachbereich(e)/-gebiet(e): 11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Dünne Schichten
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft
11 Fachbereich Material- und Geowissenschaften
Hinterlegungsdatum: 21 Apr 2015 10:53
Letzte Änderung: 21 Apr 2015 10:53
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