Clemens, Oliver ; Rongeat, Carine ; Reddy, M. Anji ; Giehr, Andreas ; Fichtner, Maximilian ; Hahn, Horst (2014)
Electrochemical fluorination of perovskite type BaFeO2.5.
In: Dalton Trans., 43 (42)
doi: 10.1039/c4dt02485k
Artikel, Bibliographie
Kurzbeschreibung (Abstract)
Here we report on the first electrochemical fluorination exemplarily performed on perovskite type BaFeO2.5. A cell setup of the type BaFeO2.5 II La0.9Ba0.1F2.9 II MFx (with MFx being MgF2 and CeF3) was used to perform the reaction, charging the cell up to voltages of about 4 V. Formation of a compound of approximate composition BaFeO2.5F[similar]0.5 was observed, in agreement with diffraction studies of the independently performed chemically fluorinated compound using F2 gas, and also possessing a capacity which is close to the theoretical capacity of the material. This new method gives an alternative towards the use of highly reactive and toxic F2 gas, and provides potential in adjusting the chemical potential for oxidative chemical fluorinations.
| Typ des Eintrags: | Artikel |
|---|---|
| Erschienen: | 2014 |
| Autor(en): | Clemens, Oliver ; Rongeat, Carine ; Reddy, M. Anji ; Giehr, Andreas ; Fichtner, Maximilian ; Hahn, Horst |
| Art des Eintrags: | Bibliographie |
| Titel: | Electrochemical fluorination of perovskite type BaFeO2.5 |
| Sprache: | Englisch |
| Publikationsjahr: | 14 November 2014 |
| Verlag: | The Royal Society of Chemistry Publishing |
| Titel der Zeitschrift, Zeitung oder Schriftenreihe: | Dalton Trans. |
| Jahrgang/Volume einer Zeitschrift: | 43 |
| (Heft-)Nummer: | 42 |
| DOI: | 10.1039/c4dt02485k |
| Kurzbeschreibung (Abstract): | Here we report on the first electrochemical fluorination exemplarily performed on perovskite type BaFeO2.5. A cell setup of the type BaFeO2.5 II La0.9Ba0.1F2.9 II MFx (with MFx being MgF2 and CeF3) was used to perform the reaction, charging the cell up to voltages of about 4 V. Formation of a compound of approximate composition BaFeO2.5F[similar]0.5 was observed, in agreement with diffraction studies of the independently performed chemically fluorinated compound using F2 gas, and also possessing a capacity which is close to the theoretical capacity of the material. This new method gives an alternative towards the use of highly reactive and toxic F2 gas, and provides potential in adjusting the chemical potential for oxidative chemical fluorinations. |
| Fachbereich(e)/-gebiet(e): | 11 Fachbereich Material- und Geowissenschaften 11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft 11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Materialdesign durch Synthese 11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Gemeinschaftslabor Nanomaterialien |
| Hinterlegungsdatum: | 16 Feb 2015 13:11 |
| Letzte Änderung: | 12 Apr 2017 12:23 |
| PPN: | |
| Sponsoren: | Financial support by the State of Baden-Wurttemberg, Project house e-drive (#PHed.L.0208.01) is gratefully acknowledged., Horst Hahn appreciates the support of the State of Hesse by an equipment grant. |
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