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Microstructure and magnetic properties of Mn–Al–C alloy powders prepared by ball milling

Jian, Hong ; Skokov, Konstantin P. ; Gutfleisch, Oliver (2015)
Microstructure and magnetic properties of Mn–Al–C alloy powders prepared by ball milling.
In: Journal of Alloys and Compounds, 622
doi: 10.1016/j.jallcom.2014.https://doi.org/10.138
Artikel, Bibliographie

Kurzbeschreibung (Abstract)

Magnetically anisotropic Mn–Al–C powders have been prepared by ball milling the τ-phase Mn53.3Al45C1.7 alloy. Flake-shaped powders were obtained after milling for 2 h and the thickness decreased continuously with extended milling time. No sign of decomposition was observed in the as-milled state, however, magnetization decreased and coercivity increased continuously with milling time because of the defects introduced in the milling process. μ0iHc of 0.52 T was obtained in powders milled for 12 h. By annealing the as-milled powders at 773 K for 30 min, the magnetization increased significantly because of the recovered crystal structure of τ-phase. A degree of texture ranging from 17.8% to 37.1% has been obtained and the magnetically easy axis lies within the plane of the flakes. Optimized magnetic properties, with Mr of 54.8 Am2 kg−1 and μ0iHc of 0.28 T, was obtained in Mn53.3Al45C1.7 powders milled for 5 h followed by heat treatment at 773 K.

Typ des Eintrags: Artikel
Erschienen: 2015
Autor(en): Jian, Hong ; Skokov, Konstantin P. ; Gutfleisch, Oliver
Art des Eintrags: Bibliographie
Titel: Microstructure and magnetic properties of Mn–Al–C alloy powders prepared by ball milling
Sprache: Englisch
Publikationsjahr: 15 Februar 2015
Verlag: Elsevier Science Publishing
Titel der Zeitschrift, Zeitung oder Schriftenreihe: Journal of Alloys and Compounds
Jahrgang/Volume einer Zeitschrift: 622
DOI: 10.1016/j.jallcom.2014.https://doi.org/10.138
Kurzbeschreibung (Abstract):

Magnetically anisotropic Mn–Al–C powders have been prepared by ball milling the τ-phase Mn53.3Al45C1.7 alloy. Flake-shaped powders were obtained after milling for 2 h and the thickness decreased continuously with extended milling time. No sign of decomposition was observed in the as-milled state, however, magnetization decreased and coercivity increased continuously with milling time because of the defects introduced in the milling process. μ0iHc of 0.52 T was obtained in powders milled for 12 h. By annealing the as-milled powders at 773 K for 30 min, the magnetization increased significantly because of the recovered crystal structure of τ-phase. A degree of texture ranging from 17.8% to 37.1% has been obtained and the magnetically easy axis lies within the plane of the flakes. Optimized magnetic properties, with Mr of 54.8 Am2 kg−1 and μ0iHc of 0.28 T, was obtained in Mn53.3Al45C1.7 powders milled for 5 h followed by heat treatment at 773 K.

Freie Schlagworte: Mn–Al–C alloy, Mechanical milling, Permanent magnets
Fachbereich(e)/-gebiet(e): 11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Funktionale Materialien
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft
11 Fachbereich Material- und Geowissenschaften
Hinterlegungsdatum: 03 Dez 2014 11:57
Letzte Änderung: 03 Dez 2014 11:57
PPN:
Sponsoren: The research leading to these results has received funding from the European Community’s Seventh Framework Programme FP7/2007-2013 under grant agreement No. 280670 ‘REFREEPERMAG’., H. J. is grateful to the China Scholarship Council for financial support. K. P. S. is thankful for the G8 project., Financial support by the German federal state of Hessen through its excellent programme LOEWE “RESPONSE” is gratefully acknowledged.
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