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Recent Advances in Solid State NMR of Small Molecules in Confinement

Werner, M. and Rothermel, N. and Breitzke, H. and Gutmann, T. and Buntkowsky, G. (2014):
Recent Advances in Solid State NMR of Small Molecules in Confinement.
In: Israel Journal of Chemistry, pp. 60-73, 54, (1-2), [Online-Edition: http://apps.webofknowledge.com/full_record.do?product=WOS&se...],
[Article]

Abstract

In the past years, porous media have become a major focus of materials science, due to their versatile properties, such as high surface area, low specific weight, high surface functionality, and the ability to customize their surface properties. Applications of porous media range from catalysis to separation media to gas storage. All of the mentioned applications involve the introduction of guest molecules into the pores. For efficient application of the materials, it is essential to know the behavior of these introduced molecules in the confined state. Solid state (ss) NMR gives a unique insight into the dynamics, the guest-host interactions, and the binding sites of porous materials and is probably the most powerful characterization method for probing a huge variety of real-life systems. Recent results in research of microporous zeolites and periodically mesoporous silica (PMS) materials using NMR will be highlighted.

Item Type: Article
Erschienen: 2014
Creators: Werner, M. and Rothermel, N. and Breitzke, H. and Gutmann, T. and Buntkowsky, G.
Title: Recent Advances in Solid State NMR of Small Molecules in Confinement
Language: English
Abstract:

In the past years, porous media have become a major focus of materials science, due to their versatile properties, such as high surface area, low specific weight, high surface functionality, and the ability to customize their surface properties. Applications of porous media range from catalysis to separation media to gas storage. All of the mentioned applications involve the introduction of guest molecules into the pores. For efficient application of the materials, it is essential to know the behavior of these introduced molecules in the confined state. Solid state (ss) NMR gives a unique insight into the dynamics, the guest-host interactions, and the binding sites of porous materials and is probably the most powerful characterization method for probing a huge variety of real-life systems. Recent results in research of microporous zeolites and periodically mesoporous silica (PMS) materials using NMR will be highlighted.

Journal or Publication Title: Israel Journal of Chemistry
Volume: 54
Number: 1-2
Uncontrolled Keywords: confinement guest-host mesoporous microporous porous media solid state nmr zeolites dynamic nuclear-polarization angle-spinning nmr mesoporous silica materials guest-host interactions phase peptide-synthesis ionic liquids hydrogenation reactions immobilized catalysts theoretical aspects lattice-relaxation
Divisions: 07 Department of Chemistry
07 Department of Chemistry > Physical Chemistry
Date Deposited: 27 Oct 2014 20:43
Official URL: http://apps.webofknowledge.com/full_record.do?product=WOS&se...
Additional Information:

Sp. Iss. SI Ab7zi Times Cited:1 Cited References Count:121

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