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Application of Hg-199 Solid-State NMR to Hg Based HTSC

Hoffmann, W. ; Breitzke, H. ; Baenitz, M. ; Heinze, M. ; Lüders, K. ; Buntkowsky, G. ; Limbach, H. H. ; Antipov, E. V. ; Gippius, A. A. ; Loebich, O. ; Khan, H. R. ; Paranthaman, M. ; Thompson, J. R. (1994)
Application of Hg-199 Solid-State NMR to Hg Based HTSC.
In: Physica C, 227 (3-4)
Artikel, Bibliographie

Kurzbeschreibung (Abstract)

It is proposed to study Hg-oxide ceramics, which are high-temperature superconductors, with Hg-199 NMR spectroscopy. As an exemplary application of this method first room-temperature Hg-199 spectra and spin-lattice relaxation times of samples with different macrostructure are presented. A spin-lattice relaxation time of T1 = 35 ms is found. All samples exhibit similar characteristic powder spectra caused by an axially symmetric Hg-199 spin interaction. The isotropic value and the anisotropy of the tensor relative to solid HgCl2 as a standard substance is estimated.

Typ des Eintrags: Artikel
Erschienen: 1994
Autor(en): Hoffmann, W. ; Breitzke, H. ; Baenitz, M. ; Heinze, M. ; Lüders, K. ; Buntkowsky, G. ; Limbach, H. H. ; Antipov, E. V. ; Gippius, A. A. ; Loebich, O. ; Khan, H. R. ; Paranthaman, M. ; Thompson, J. R.
Art des Eintrags: Bibliographie
Titel: Application of Hg-199 Solid-State NMR to Hg Based HTSC
Sprache: Englisch
Publikationsjahr: 1994
Titel der Zeitschrift, Zeitung oder Schriftenreihe: Physica C
Jahrgang/Volume einer Zeitschrift: 227
(Heft-)Nummer: 3-4
URL / URN: http://apps.webofknowledge.com/full_record.do?product=WOS&se...
Kurzbeschreibung (Abstract):

It is proposed to study Hg-oxide ceramics, which are high-temperature superconductors, with Hg-199 NMR spectroscopy. As an exemplary application of this method first room-temperature Hg-199 spectra and spin-lattice relaxation times of samples with different macrostructure are presented. A spin-lattice relaxation time of T1 = 35 ms is found. All samples exhibit similar characteristic powder spectra caused by an axially symmetric Hg-199 spin interaction. The isotropic value and the anisotropy of the tensor relative to solid HgCl2 as a standard substance is estimated.

Freie Schlagworte: high-tc-superconductor nqr cu hgba2cacu2o6+delta hgba2cuo4+delta ba2ycu3o7 shifts salts
Zusätzliche Informationen:

Nx699 Times Cited:5 Cited References Count:19

Fachbereich(e)/-gebiet(e): 07 Fachbereich Chemie
07 Fachbereich Chemie > Eduard Zintl-Institut > Fachgebiet Physikalische Chemie
Hinterlegungsdatum: 27 Okt 2014 20:50
Letzte Änderung: 29 Mai 2019 08:45
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