Scheid, D. ; Lederle, C. ; Vowinkel, S. ; Schäfer, C. G. ; Stühn, B. ; Gallei, M.
:
Redox- and mechano-chromic response of metallopolymer-based elastomeric colloidal crystal films.
[Online-Edition: http://dx.doi.org/10.1039/C3TC32525C]
In:
J. Mater. Chem. C, 2
S. 2583-2590.
[Artikel]
, (2014)
Kurzbeschreibung (Abstract)
A novel and convenient route for the preparation of monodisperse ferrocene-containing core-interlayer-shell particles using emulsion polymerisation protocols is described. These metallopolymer-based particles can be used to produce highly ordered elastomeric opal films with fascinating distinct reflection colours. The present work additionally describes the combined addressability of both stimuli, redox-chemistry and mechanical stress. The obtained materials are interesting since application of the melt-shear process followed by crosslinking of the matrix provides access to large-area, mechano-responsive elastomeric opal films featuring an additional redox response. Both, basic synthesis aspects and first steps towards application in the field of stimuli-responsive sensing of respective materials are discussed.
| Typ des Eintrags: | Artikel |
|---|---|
| Erschienen: | 2014 |
| Autor(en): | Scheid, D. ; Lederle, C. ; Vowinkel, S. ; Schäfer, C. G. ; Stühn, B. ; Gallei, M. |
| Titel: | Redox- and mechano-chromic response of metallopolymer-based elastomeric colloidal crystal films |
| Sprache: | Deutsch |
| Kurzbeschreibung (Abstract): | A novel and convenient route for the preparation of monodisperse ferrocene-containing core-interlayer-shell particles using emulsion polymerisation protocols is described. These metallopolymer-based particles can be used to produce highly ordered elastomeric opal films with fascinating distinct reflection colours. The present work additionally describes the combined addressability of both stimuli, redox-chemistry and mechanical stress. The obtained materials are interesting since application of the melt-shear process followed by crosslinking of the matrix provides access to large-area, mechano-responsive elastomeric opal films featuring an additional redox response. Both, basic synthesis aspects and first steps towards application in the field of stimuli-responsive sensing of respective materials are discussed. |
| Titel der Zeitschrift, Zeitung oder Schriftenreihe: | J. Mater. Chem. C |
| Band: | 2 |
| Verlag: | The Royal Society of Chemistry |
| Fachbereich(e)/-gebiet(e): | 05 Fachbereich Physik 05 Fachbereich Physik > Institut für Festkörperphysik 05 Fachbereich Physik > Institut für Festkörperphysik > Experimentelle Physik kondensierter Materie |
| Hinterlegungsdatum: | 29 Jul 2014 12:59 |
| Offizielle URL: | http://dx.doi.org/10.1039/C3TC32525C |
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