Scheid, D. and Lederle, C. and Vowinkel, S. and Schäfer, C. G. and Stühn, B. and Gallei, M. (2014):
Redox- and mechano-chromic response of metallopolymer-based elastomeric colloidal crystal films.
In: J. Mater. Chem. C, 2, pp. 2583-2590. The Royal Society of Chemistry, [Article]
Abstract
A novel and convenient route for the preparation of monodisperse ferrocene-containing core-interlayer-shell particles using emulsion polymerisation protocols is described. These metallopolymer-based particles can be used to produce highly ordered elastomeric opal films with fascinating distinct reflection colours. The present work additionally describes the combined addressability of both stimuli, redox-chemistry and mechanical stress. The obtained materials are interesting since application of the melt-shear process followed by crosslinking of the matrix provides access to large-area, mechano-responsive elastomeric opal films featuring an additional redox response. Both, basic synthesis aspects and first steps towards application in the field of stimuli-responsive sensing of respective materials are discussed.
Item Type: | Article |
---|---|
Erschienen: | 2014 |
Creators: | Scheid, D. and Lederle, C. and Vowinkel, S. and Schäfer, C. G. and Stühn, B. and Gallei, M. |
Title: | Redox- and mechano-chromic response of metallopolymer-based elastomeric colloidal crystal films |
Language: | German |
Abstract: | A novel and convenient route for the preparation of monodisperse ferrocene-containing core-interlayer-shell particles using emulsion polymerisation protocols is described. These metallopolymer-based particles can be used to produce highly ordered elastomeric opal films with fascinating distinct reflection colours. The present work additionally describes the combined addressability of both stimuli, redox-chemistry and mechanical stress. The obtained materials are interesting since application of the melt-shear process followed by crosslinking of the matrix provides access to large-area, mechano-responsive elastomeric opal films featuring an additional redox response. Both, basic synthesis aspects and first steps towards application in the field of stimuli-responsive sensing of respective materials are discussed. |
Journal or Publication Title: | J. Mater. Chem. C |
Journal volume: | 2 |
Publisher: | The Royal Society of Chemistry |
Divisions: | 05 Department of Physics 05 Department of Physics > Institute for condensed matter physics 05 Department of Physics > Institute for condensed matter physics > Experimental Condensed Matter Physics |
Date Deposited: | 29 Jul 2014 12:59 |
Official URL: | http://dx.doi.org/10.1039/C3TC32525C |
Export: | |
Suche nach Titel in: | TUfind oder in Google |
![]() |
Send an inquiry |
Options (only for editors)
![]() |
Show editorial Details |