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Redox- and mechano-chromic response of metallopolymer-based elastomeric colloidal crystal films

Scheid, D. ; Lederle, C. ; Vowinkel, S. ; Schäfer, C. G. ; Stühn, B. ; Gallei, M. :
Redox- and mechano-chromic response of metallopolymer-based elastomeric colloidal crystal films.
[Online-Edition: http://dx.doi.org/10.1039/C3TC32525C]
In: J. Mater. Chem. C, 2 pp. 2583-2590.
[Artikel] , (2014)

Offizielle URL: http://dx.doi.org/10.1039/C3TC32525C

Kurzbeschreibung (Abstract)

A novel and convenient route for the preparation of monodisperse ferrocene-containing core-interlayer-shell particles using emulsion polymerisation protocols is described. These metallopolymer-based particles can be used to produce highly ordered elastomeric opal films with fascinating distinct reflection colours. The present work additionally describes the combined addressability of both stimuli, redox-chemistry and mechanical stress. The obtained materials are interesting since application of the melt-shear process followed by crosslinking of the matrix provides access to large-area, mechano-responsive elastomeric opal films featuring an additional redox response. Both, basic synthesis aspects and first steps towards application in the field of stimuli-responsive sensing of respective materials are discussed.

Typ des Eintrags: Artikel
Erschienen: 2014
Autor(en): Scheid, D. ; Lederle, C. ; Vowinkel, S. ; Schäfer, C. G. ; Stühn, B. ; Gallei, M.
Titel: Redox- and mechano-chromic response of metallopolymer-based elastomeric colloidal crystal films
Sprache: Deutsch
Kurzbeschreibung (Abstract):

A novel and convenient route for the preparation of monodisperse ferrocene-containing core-interlayer-shell particles using emulsion polymerisation protocols is described. These metallopolymer-based particles can be used to produce highly ordered elastomeric opal films with fascinating distinct reflection colours. The present work additionally describes the combined addressability of both stimuli, redox-chemistry and mechanical stress. The obtained materials are interesting since application of the melt-shear process followed by crosslinking of the matrix provides access to large-area, mechano-responsive elastomeric opal films featuring an additional redox response. Both, basic synthesis aspects and first steps towards application in the field of stimuli-responsive sensing of respective materials are discussed.

Titel der Zeitschrift, Zeitung oder Schriftenreihe: J. Mater. Chem. C
Band: 2
Verlag: The Royal Society of Chemistry
Fachbereich(e)/-gebiet(e): 05 Fachbereich Physik
05 Fachbereich Physik > Institut für Festkörperphysik
05 Fachbereich Physik > Institut für Festkörperphysik > Experimentelle Physik kondensierter Materie
Hinterlegungsdatum: 29 Jul 2014 12:59
Offizielle URL: http://dx.doi.org/10.1039/C3TC32525C
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