Scheid, D. and Lederle, C. and Vowinkel, S. and Schäfer, C. G. and Stühn, B. and Gallei, M. (2014):
Redox- and mechano-chromic response of metallopolymer-based elastomeric colloidal crystal films.
In: J. Mater. Chem. C, The Royal Society of Chemistry, pp. 2583-2590, 2, [Online-Edition: http://dx.doi.org/10.1039/C3TC32525C],
[Article]
Abstract
A novel and convenient route for the preparation of monodisperse ferrocene-containing core-interlayer-shell particles using emulsion polymerisation protocols is described. These metallopolymer-based particles can be used to produce highly ordered elastomeric opal films with fascinating distinct reflection colours. The present work additionally describes the combined addressability of both stimuli, redox-chemistry and mechanical stress. The obtained materials are interesting since application of the melt-shear process followed by crosslinking of the matrix provides access to large-area, mechano-responsive elastomeric opal films featuring an additional redox response. Both, basic synthesis aspects and first steps towards application in the field of stimuli-responsive sensing of respective materials are discussed.
| Item Type: | Article |
|---|---|
| Erschienen: | 2014 |
| Creators: | Scheid, D. and Lederle, C. and Vowinkel, S. and Schäfer, C. G. and Stühn, B. and Gallei, M. |
| Title: | Redox- and mechano-chromic response of metallopolymer-based elastomeric colloidal crystal films |
| Language: | German |
| Abstract: | A novel and convenient route for the preparation of monodisperse ferrocene-containing core-interlayer-shell particles using emulsion polymerisation protocols is described. These metallopolymer-based particles can be used to produce highly ordered elastomeric opal films with fascinating distinct reflection colours. The present work additionally describes the combined addressability of both stimuli, redox-chemistry and mechanical stress. The obtained materials are interesting since application of the melt-shear process followed by crosslinking of the matrix provides access to large-area, mechano-responsive elastomeric opal films featuring an additional redox response. Both, basic synthesis aspects and first steps towards application in the field of stimuli-responsive sensing of respective materials are discussed. |
| Journal or Publication Title: | J. Mater. Chem. C |
| Volume: | 2 |
| Publisher: | The Royal Society of Chemistry |
| Divisions: | 05 Department of Physics 05 Department of Physics > Institute for condensed matter physics 05 Department of Physics > Institute for condensed matter physics > Experimental Condensed Matter Physics |
| Date Deposited: | 29 Jul 2014 12:59 |
| Official URL: | http://dx.doi.org/10.1039/C3TC32525C |
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