Sapper, Eva and Novak, Nikola and Jo, Wook and Granzow, Torsten and Rödel, Jürgen (2014):
Electric-field–temperature phase diagram of the ferroelectric relaxor system (1 − x)Bi1/2Na1/2TiO3 − xBaTiO3 doped with manganese.
In: Journal of Applied Physics, pp. 194104(1-7), 115, (19), ISSN 0021-8979,
[Online-Edition: http://dx.doi.org/10.1063/1.4876746],
[Article]
Abstract
The electric-field–temperature phase diagram for the lead-free relaxor material (1 − x)(Bi1/2Na1/2)TiO3 − xBaTiO3 (x = 0.03, 0.06, and 0.09) doped with 0.5 mol% Mn (BNT-100xBT:Mn) was established. Transition lines between ergodic or nonergodic relaxor states and the field-induced ferroelectric state were determined at constant temperatures with electric-field-dependent measurements of the polarization as well as of the piezoelectric coefficient and permittivity. Near the depolarization temperature T d, the switching between two ferroelectric poling directions occurs in two steps via an intermediate relaxor state. This effect is closely related to the pinching of the ferroelectric hysteresis loop.
| Item Type: | Article |
|---|---|
| Erschienen: | 2014 |
| Creators: | Sapper, Eva and Novak, Nikola and Jo, Wook and Granzow, Torsten and Rödel, Jürgen |
| Title: | Electric-field–temperature phase diagram of the ferroelectric relaxor system (1 − x)Bi1/2Na1/2TiO3 − xBaTiO3 doped with manganese |
| Language: | English |
| Abstract: | The electric-field–temperature phase diagram for the lead-free relaxor material (1 − x)(Bi1/2Na1/2)TiO3 − xBaTiO3 (x = 0.03, 0.06, and 0.09) doped with 0.5 mol% Mn (BNT-100xBT:Mn) was established. Transition lines between ergodic or nonergodic relaxor states and the field-induced ferroelectric state were determined at constant temperatures with electric-field-dependent measurements of the polarization as well as of the piezoelectric coefficient and permittivity. Near the depolarization temperature T d, the switching between two ferroelectric poling directions occurs in two steps via an intermediate relaxor state. This effect is closely related to the pinching of the ferroelectric hysteresis loop. |
| Journal or Publication Title: | Journal of Applied Physics |
| Volume: | 115 |
| Number: | 19 |
| Uncontrolled Keywords: | Relaxor ferroelectrics; Polarization; Piezoelectric fields; Ferroelectric phase transitions; Phase diagrams |
| Divisions: | 11 Department of Materials and Earth Sciences 11 Department of Materials and Earth Sciences > Material Science 11 Department of Materials and Earth Sciences > Material Science > Nonmetallic-Inorganic Materials Zentrale Einrichtungen DFG-Collaborative Research Centres (incl. Transregio) > Collaborative Research Centres > CRC 595: Electrical fatigue DFG-Collaborative Research Centres (incl. Transregio) > Collaborative Research Centres > CRC 595: Electrical fatigue > A - Synthesis > Subproject A1: Manufacturing of ceramic, textured actuators with high strain DFG-Collaborative Research Centres (incl. Transregio) > Collaborative Research Centres > CRC 595: Electrical fatigue > D - Component properties DFG-Collaborative Research Centres (incl. Transregio) > Collaborative Research Centres > CRC 595: Electrical fatigue > D - Component properties > Subproject D1: Mesoscopic and macroscopic fatigue in doped ferroelectric ceramics DFG-Collaborative Research Centres (incl. Transregio) > Collaborative Research Centres > CRC 595: Electrical fatigue > A - Synthesis DFG-Collaborative Research Centres (incl. Transregio) > Collaborative Research Centres DFG-Collaborative Research Centres (incl. Transregio) |
| Date Deposited: | 26 May 2014 07:44 |
| Official URL: | http://dx.doi.org/10.1063/1.4876746 |
| Additional Information: | SFB 595 Cooperation A1, D1 |
| Identification Number: | doi:10.1063/1.4876746 |
| Funders: | This work was financed by the Deutsche Forschungsgemeinschaft (DFG) under the SFB595, project D1. |
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