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Tailoring Strain Properties of (0.94−x)Bi1/2Na1/2TiO3-0.06BaTiO3-xK0.5Na0.5NbO3Ferroelectric/Relaxor Composites

Groh, Claudia ; Jo, Wook ; Rödel, Jürgen (2014)
Tailoring Strain Properties of (0.94−x)Bi1/2Na1/2TiO3-0.06BaTiO3-xK0.5Na0.5NbO3Ferroelectric/Relaxor Composites.
In: Journal of the American Ceramic Society, 97 (5)
doi: 10.1111/jace.12783
Artikel, Bibliographie

Kurzbeschreibung (Abstract)

A remarkable progress in the quest of lead-free piezoceramics for actuator applications has been made with the development of incipient piezoceramics featured by giant strains. A drawback, however, is the high electric field required to generate this giant strain. A powerful approach to overcoming this drawback lies in relaxor/ferroelectric (FE) composites comprised such giant strain materials (matrix) and a FE or nonergodic relaxor (seed). In this study, we investigate the effect of K0.5Na0.5NbO3 content in the matrix and the volume ratio of seed to matrix using composites of 0.93Bi1/2Na1/2TiO3–0.07BaTiO3 as a seed and (0.94 − x)Bi1/2Na1/2TiO3–0.06BaTiO3–xK0.5Na0.5NbO3 as a matrix. The strain of all matrices, independent of their K0.5Na0.5NbO3 content, was found to be enhanced by adding a certain amount of seed. An optimum strain is achieved for the composite comprised of a matrix with x = 0.02 K0.5Na0.5NbO3 and 10% seed. By means of a differential analysis on the temperature-dependent dielectric permittivity, it was shown that the seed phase is still present in the composites despite the naturally expected diffusion process during sintering.

Typ des Eintrags: Artikel
Erschienen: 2014
Autor(en): Groh, Claudia ; Jo, Wook ; Rödel, Jürgen
Art des Eintrags: Bibliographie
Titel: Tailoring Strain Properties of (0.94−x)Bi1/2Na1/2TiO3-0.06BaTiO3-xK0.5Na0.5NbO3Ferroelectric/Relaxor Composites
Sprache: Englisch
Publikationsjahr: 14 Mai 2014
Titel der Zeitschrift, Zeitung oder Schriftenreihe: Journal of the American Ceramic Society
Jahrgang/Volume einer Zeitschrift: 97
(Heft-)Nummer: 5
DOI: 10.1111/jace.12783
Kurzbeschreibung (Abstract):

A remarkable progress in the quest of lead-free piezoceramics for actuator applications has been made with the development of incipient piezoceramics featured by giant strains. A drawback, however, is the high electric field required to generate this giant strain. A powerful approach to overcoming this drawback lies in relaxor/ferroelectric (FE) composites comprised such giant strain materials (matrix) and a FE or nonergodic relaxor (seed). In this study, we investigate the effect of K0.5Na0.5NbO3 content in the matrix and the volume ratio of seed to matrix using composites of 0.93Bi1/2Na1/2TiO3–0.07BaTiO3 as a seed and (0.94 − x)Bi1/2Na1/2TiO3–0.06BaTiO3–xK0.5Na0.5NbO3 as a matrix. The strain of all matrices, independent of their K0.5Na0.5NbO3 content, was found to be enhanced by adding a certain amount of seed. An optimum strain is achieved for the composite comprised of a matrix with x = 0.02 K0.5Na0.5NbO3 and 10% seed. By means of a differential analysis on the temperature-dependent dielectric permittivity, it was shown that the seed phase is still present in the composites despite the naturally expected diffusion process during sintering.

Fachbereich(e)/-gebiet(e): 11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Nichtmetallisch-Anorganische Werkstoffe
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft
11 Fachbereich Material- und Geowissenschaften
Hinterlegungsdatum: 19 Mai 2014 09:37
Letzte Änderung: 19 Jan 2015 13:08
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Sponsoren: Adria
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