Franzbach, Daniel and Seo, Yo-Han and Studer, Andrew J. and Zhang, Yichi and Glaum, Julia and Daniels, John E. and Koruza, Jurij and Benčan, Andreja and Malič, Barbara and Webber, Kyle G. (2014):
Electric-field-induced phase transitions in co-doped Pb(Zr1−xTix)O3at the morphotropic phase boundary.
In: Science and Technology of Advanced Materials, 15 (1), pp. 015010(1-11). ISSN 1468-6996,
[Article]
Abstract
The strain- and polarization-electric field behavior was characterized at room temperature for Pb0.98Ba0.01(Zr1−xTix)0.98Nb0.02O3, 0.40 ≤ x ≤ 0.60. The investigated compositions were located in the vicinity of the morphotropic phase boundary, giving insight into the influence of crystal structure on the hysteretic ferroelectric behavior. The remanent strain of particular compositions is shown to be larger than theoretically allowed by ferroelectric switching alone, indicating the presence of additional remanent strain mechanisms. A phenomenological free energy analysis was used to simulate the effect of an applied electric field on the initial equilibrium phase. It is shown that electric-field-induced phase transitions in polycrystalline ferroelectrics can account for the experimental observations. The experimental and simulation results are contrasted to neutron diffraction measurements performed on representative compositions in the virgin and remanent states.
| Item Type: | Article |
|---|---|
| Erschienen: | 2014 |
| Creators: | Franzbach, Daniel and Seo, Yo-Han and Studer, Andrew J. and Zhang, Yichi and Glaum, Julia and Daniels, John E. and Koruza, Jurij and Benčan, Andreja and Malič, Barbara and Webber, Kyle G. |
| Title: | Electric-field-induced phase transitions in co-doped Pb(Zr1−xTix)O3at the morphotropic phase boundary |
| Language: | English |
| Abstract: | The strain- and polarization-electric field behavior was characterized at room temperature for Pb0.98Ba0.01(Zr1−xTix)0.98Nb0.02O3, 0.40 ≤ x ≤ 0.60. The investigated compositions were located in the vicinity of the morphotropic phase boundary, giving insight into the influence of crystal structure on the hysteretic ferroelectric behavior. The remanent strain of particular compositions is shown to be larger than theoretically allowed by ferroelectric switching alone, indicating the presence of additional remanent strain mechanisms. A phenomenological free energy analysis was used to simulate the effect of an applied electric field on the initial equilibrium phase. It is shown that electric-field-induced phase transitions in polycrystalline ferroelectrics can account for the experimental observations. The experimental and simulation results are contrasted to neutron diffraction measurements performed on representative compositions in the virgin and remanent states. |
| Journal or Publication Title: | Science and Technology of Advanced Materials |
| Journal volume: | 15 |
| Number: | 1 |
| Divisions: | 11 Department of Materials and Earth Sciences > Material Science > Elektromechanik von Oxiden 11 Department of Materials and Earth Sciences > Material Science > Nonmetallic-Inorganic Materials 11 Department of Materials and Earth Sciences > Material Science 11 Department of Materials and Earth Sciences Zentrale Einrichtungen Exzellenzinitiative Exzellenzinitiative > Graduate Schools > Graduate School of Computational Engineering (CE) Exzellenzinitiative > Graduate Schools |
| Date Deposited: | 14 Apr 2014 11:01 |
| Official URL: | http://dx.doi.org/10.1088/1468-6996/15/1/015010 |
| Identification Number: | doi:10.1088/1468-6996/15/1/015010 |
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