TU Darmstadt / ULB / TUbiblio

Single-Source Magnetic Nanorattles By Using Convenient Emulsion Polymerization Protocols

Scheid, Daniel and Cherkashinin, Gennady and Ionescu, Emanuel and Gallei, Markus (2014):
Single-Source Magnetic Nanorattles By Using Convenient Emulsion Polymerization Protocols.
In: Langmuir, ACS Publications, pp. 1204-1209, 30, (5), ISSN 0743-7463,
[Online-Edition: http://dx.doi.org/10.1021/la404285c],
[Article]

Abstract

A novel strategy to achieve easily scalable magneto-responsive nanoceramics with core/shell and nanorattle-type or yolk/shell architectures based on a ferrocene-containing polymer precursor is described. Monodisperse nanorattle-type magnetic particles are obtained by using convenient semicontinuous emulsion polymerization and Stöber process protocols followed by thermal treatment. The particles are characterized by TGA, TEM, WAXS, DLS, XPS, and Raman spectroscopy. Herein, established synthetic protocols widen opportunities for the convenient bottom-up strategies of various ferrocene-precursor-based spherical architectures for advanced ceramics with potential applications within fields of sensing and stimuli-responsive nanophotonics.

Item Type: Article
Erschienen: 2014
Creators: Scheid, Daniel and Cherkashinin, Gennady and Ionescu, Emanuel and Gallei, Markus
Title: Single-Source Magnetic Nanorattles By Using Convenient Emulsion Polymerization Protocols
Language: English
Abstract:

A novel strategy to achieve easily scalable magneto-responsive nanoceramics with core/shell and nanorattle-type or yolk/shell architectures based on a ferrocene-containing polymer precursor is described. Monodisperse nanorattle-type magnetic particles are obtained by using convenient semicontinuous emulsion polymerization and Stöber process protocols followed by thermal treatment. The particles are characterized by TGA, TEM, WAXS, DLS, XPS, and Raman spectroscopy. Herein, established synthetic protocols widen opportunities for the convenient bottom-up strategies of various ferrocene-precursor-based spherical architectures for advanced ceramics with potential applications within fields of sensing and stimuli-responsive nanophotonics.

Journal or Publication Title: Langmuir
Volume: 30
Number: 5
Publisher: ACS Publications
Divisions: 11 Department of Materials and Earth Sciences > Material Science > Dispersive Solids
11 Department of Materials and Earth Sciences > Material Science > Surface Science
07 Department of Chemistry > Fachgebiet Makromolekulare Chemie
11 Department of Materials and Earth Sciences > Material Science
11 Department of Materials and Earth Sciences
07 Department of Chemistry
Date Deposited: 20 Mar 2014 09:40
Official URL: http://dx.doi.org/10.1021/la404285c
Identification Number: doi:10.1021/la404285c
Funders: The authors want to thank the Landesoffensive zur Entwicklung Wissenschaftlich-ökonomischer Exzellenz (LOEWE Soft Control) for ongoing financial support of this work.
Export:

Optionen (nur für Redakteure)

View Item View Item