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Influence of diamond particles content on the critical load for crack initiation and fracture toughness of SiOC glass–diamond composites

Sellappan, Pathikumar ; Guin, Jean-Pierre ; Rocherulle, Jean ; Celarie, Fabrice ; Rouxel, Tanguy ; Riedel, Ralf (2013)
Influence of diamond particles content on the critical load for crack initiation and fracture toughness of SiOC glass–diamond composites.
In: Journal of the European Ceramic Society, 33 (4)
doi: 10.1016/j.jeurceramsoc.2012.10.012
Artikel, Bibliographie

Kurzbeschreibung (Abstract)

The crack initiation load and fracture toughness were characterized as a function of diamond particle content, up to 25 vol%, in silicon oxycarbide glass matrix by means of Vickers indentation and single edge notch beam (SENB) technique, respectively. The larger fracture toughness value of 3.21 ± 0.3 MPa m1/2 was reached for 20 vol% diamond content composites and the value was 4 times higher than that of the unreinforced glass. The addition of diamond particles greatly influenced the crack initiation load, which increased from 2.9 to 49.0 N. The enhancement in the fracture toughness and crack initiation load can be explained by both the intrinsic mechanical properties of diamond (especially the elastic properties; E ∼ 1100 GPa) and the diamond/SiOC glass interfacial bonding. A clear correlation was found between the fracture energy, the reinforced interparticle spacing and the residual stress arising upon cooling due to thermal expansion mismatch between the matrix and the diamond particles.

Typ des Eintrags: Artikel
Erschienen: 2013
Autor(en): Sellappan, Pathikumar ; Guin, Jean-Pierre ; Rocherulle, Jean ; Celarie, Fabrice ; Rouxel, Tanguy ; Riedel, Ralf
Art des Eintrags: Bibliographie
Titel: Influence of diamond particles content on the critical load for crack initiation and fracture toughness of SiOC glass–diamond composites
Sprache: Englisch
Publikationsjahr: April 2013
Verlag: Elsevier Science Publishing
Titel der Zeitschrift, Zeitung oder Schriftenreihe: Journal of the European Ceramic Society
Jahrgang/Volume einer Zeitschrift: 33
(Heft-)Nummer: 4
DOI: 10.1016/j.jeurceramsoc.2012.10.012
Kurzbeschreibung (Abstract):

The crack initiation load and fracture toughness were characterized as a function of diamond particle content, up to 25 vol%, in silicon oxycarbide glass matrix by means of Vickers indentation and single edge notch beam (SENB) technique, respectively. The larger fracture toughness value of 3.21 ± 0.3 MPa m1/2 was reached for 20 vol% diamond content composites and the value was 4 times higher than that of the unreinforced glass. The addition of diamond particles greatly influenced the crack initiation load, which increased from 2.9 to 49.0 N. The enhancement in the fracture toughness and crack initiation load can be explained by both the intrinsic mechanical properties of diamond (especially the elastic properties; E ∼ 1100 GPa) and the diamond/SiOC glass interfacial bonding. A clear correlation was found between the fracture energy, the reinforced interparticle spacing and the residual stress arising upon cooling due to thermal expansion mismatch between the matrix and the diamond particles.

Freie Schlagworte: Polymer derived ceramics, Silicon oxycarbide glass–diamond composites, Fracture toughness, Crack initiation, Surface damage resistance
Fachbereich(e)/-gebiet(e): 11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Disperse Feststoffe
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft
11 Fachbereich Material- und Geowissenschaften
Hinterlegungsdatum: 04 Feb 2014 09:26
Letzte Änderung: 04 Feb 2014 09:26
PPN:
Sponsoren: P. Sellappan acknowledges the Ministry of Higher Education and Research of France for the fellowship. , Région Bretagne (Brittany, France) is acknowledged for instrumental facilities. , German Research Foundation (DFG, Priority Program 1181), Bonn, Germany, and the Fonds der Chemischen Industrie, Frankfurt, Germany, are acknowledged for financial support.
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