Schwab, Frederick ; Lucas, Martin ; Claus, Peter (2013)
Simple selective hydrogenation of benzene to cyclohexene in the presence of sodium dicyanamide.
In: Green Chemistry, 15 (3)
doi: 10.1039/C3GC36615D
Artikel, Bibliographie
Kurzbeschreibung (Abstract)
A new catalyst system was used in the liquid phase hydrogenation of benzene to cyclohexene containing only an aqueous solution of Ru/La2O3 and a very small quantity of sodium dicyanamide (NaDCA). This additive considerably improves the catalyst performance compared to DCA based ionic liquids. The effects of the amount of NaDCA and metal loading of the catalyst were investigated and a high initial selectivity to cyclohexene of 70% was reached.
| Typ des Eintrags: | Artikel |
|---|---|
| Erschienen: | 2013 |
| Autor(en): | Schwab, Frederick ; Lucas, Martin ; Claus, Peter |
| Art des Eintrags: | Bibliographie |
| Titel: | Simple selective hydrogenation of benzene to cyclohexene in the presence of sodium dicyanamide. |
| Sprache: | Englisch |
| Publikationsjahr: | 9 Januar 2013 |
| Titel der Zeitschrift, Zeitung oder Schriftenreihe: | Green Chemistry |
| Jahrgang/Volume einer Zeitschrift: | 15 |
| (Heft-)Nummer: | 3 |
| DOI: | 10.1039/C3GC36615D |
| Kurzbeschreibung (Abstract): | A new catalyst system was used in the liquid phase hydrogenation of benzene to cyclohexene containing only an aqueous solution of Ru/La2O3 and a very small quantity of sodium dicyanamide (NaDCA). This additive considerably improves the catalyst performance compared to DCA based ionic liquids. The effects of the amount of NaDCA and metal loading of the catalyst were investigated and a high initial selectivity to cyclohexene of 70% was reached. |
| Fachbereich(e)/-gebiet(e): | 07 Fachbereich Chemie 07 Fachbereich Chemie > Ernst-Berl-Institut > Fachgebiet Technische Chemie 07 Fachbereich Chemie > Ernst-Berl-Institut > Fachgebiet Technische Chemie > Technische Chemie II |
| Hinterlegungsdatum: | 28 Nov 2013 12:53 |
| Letzte Änderung: | 15 Sep 2014 12:22 |
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