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Enhanced thermal stability and hardness of Zr46Cu39.2Ag7.8Al7 bulk metallic glass with Fe addition

Xu, Yuanli ; Zhang, Yue ; Li, Jiangong ; Hahn, Horst (2010)
Enhanced thermal stability and hardness of Zr46Cu39.2Ag7.8Al7 bulk metallic glass with Fe addition.
In: Materials Science and Engineering: A, 527 (6)
doi: 10.1016/j.msea.2009.10.029
Artikel, Bibliographie

Kurzbeschreibung (Abstract)

We studied the effects of Fe addition on the thermal stability and hardness of (Zr46Cu39.2Ag7.8Al7)100−yFey (y = 0–7) bulk metallic glasses (BMGs). Both the supercooled liquid region (ΔTx) width and crystallization temperature of the (Zr46Cu39.2Ag7.8Al7)100−yFey BMGs increase with Fe addition; and the largest ΔTx of 114 K is achieved at y = 4. The average free volume decreases with increasing Fe content. The hardness increases with increasing Fe content, which may result from the decrease in free volume and the precipitation of nanocrystalline phases from glassy matrix due to Fe addition.

Typ des Eintrags: Artikel
Erschienen: 2010
Autor(en): Xu, Yuanli ; Zhang, Yue ; Li, Jiangong ; Hahn, Horst
Art des Eintrags: Bibliographie
Titel: Enhanced thermal stability and hardness of Zr46Cu39.2Ag7.8Al7 bulk metallic glass with Fe addition
Sprache: Englisch
Publikationsjahr: 15 März 2010
Verlag: Elsevier Science Publishing Company
Titel der Zeitschrift, Zeitung oder Schriftenreihe: Materials Science and Engineering: A
Jahrgang/Volume einer Zeitschrift: 527
(Heft-)Nummer: 6
DOI: 10.1016/j.msea.2009.10.029
Kurzbeschreibung (Abstract):

We studied the effects of Fe addition on the thermal stability and hardness of (Zr46Cu39.2Ag7.8Al7)100−yFey (y = 0–7) bulk metallic glasses (BMGs). Both the supercooled liquid region (ΔTx) width and crystallization temperature of the (Zr46Cu39.2Ag7.8Al7)100−yFey BMGs increase with Fe addition; and the largest ΔTx of 114 K is achieved at y = 4. The average free volume decreases with increasing Fe content. The hardness increases with increasing Fe content, which may result from the decrease in free volume and the precipitation of nanocrystalline phases from glassy matrix due to Fe addition.

Freie Schlagworte: Bulk metallic glass, Differential scanning calorimetry (DSC), Thermal stability, Hardness, Free volume
Fachbereich(e)/-gebiet(e): 11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Gemeinschaftslabor Nanomaterialien
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft
11 Fachbereich Material- und Geowissenschaften
Hinterlegungsdatum: 15 Feb 2013 10:12
Letzte Änderung: 05 Mär 2013 10:05
PPN:
Sponsoren: Financial support for this work from the International S&T Cooperation Program (ISCP) of the Chinese Ministry of Science & Technology (MOST) under Grant No. 2008DFA50340, and the Deutsche Forschungsgemeinschaft (DFG) under contract HA1344/24-1 are gratefully acknowledged.
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