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Quantitative determination of free volume in Pd40Ni40P20 bulk metallic glass

Xu, Yuanli ; Fang, Jixiang ; Gleiter, Herbert ; Hahn, Horst ; Li, Jiangong (2010)
Quantitative determination of free volume in Pd40Ni40P20 bulk metallic glass.
In: Scripta Materialia, 62 (9)
doi: 10.1016/j.scriptamat.2010.01.025
Artikel, Bibliographie

Kurzbeschreibung (Abstract)

For a long time, the determination of free volume has been a challenging problem in research on metallic glasses. An approach to determine quantitatively the free volume of metallic glasses from enthalpy measurements and calibration with the equilibrium free volume was developed and validated for as-cast and annealed Pd40Ni40P20 bulk metallic glasses. The free volume change with annealing time is in good agreement with that calculated theoretically from the free volume annihilation kinetics and that deduced from the density measurement results.

Typ des Eintrags: Artikel
Erschienen: 2010
Autor(en): Xu, Yuanli ; Fang, Jixiang ; Gleiter, Herbert ; Hahn, Horst ; Li, Jiangong
Art des Eintrags: Bibliographie
Titel: Quantitative determination of free volume in Pd40Ni40P20 bulk metallic glass
Sprache: Englisch
Publikationsjahr: Mai 2010
Verlag: Elsevier Science Publishing Company
Titel der Zeitschrift, Zeitung oder Schriftenreihe: Scripta Materialia
Jahrgang/Volume einer Zeitschrift: 62
(Heft-)Nummer: 9
DOI: 10.1016/j.scriptamat.2010.01.025
Kurzbeschreibung (Abstract):

For a long time, the determination of free volume has been a challenging problem in research on metallic glasses. An approach to determine quantitatively the free volume of metallic glasses from enthalpy measurements and calibration with the equilibrium free volume was developed and validated for as-cast and annealed Pd40Ni40P20 bulk metallic glasses. The free volume change with annealing time is in good agreement with that calculated theoretically from the free volume annihilation kinetics and that deduced from the density measurement results.

Freie Schlagworte: Bulk metallic glass, Differential scanning calorimetry (DSC), Suction casting, Annealing, Free volume
Fachbereich(e)/-gebiet(e): 11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Gemeinschaftslabor Nanomaterialien
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft
11 Fachbereich Material- und Geowissenschaften
Hinterlegungsdatum: 15 Feb 2013 10:08
Letzte Änderung: 05 Mär 2013 10:05
PPN:
Sponsoren: The present work was supported by the Deutsche Forschungsgemeinschaft (DFG) under contract HA1344/24-1 and the International S&T Cooperation Program (ISCP) of the Chinese Ministry of Science & Technology (MOST) under Grant No. 2008DFA50340., One of the authors (JF) is grateful to the Alexander-von-Humboldt Foundation for a fellowship to support his stay in Germany.
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