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Comment on: “Corrosion behaviour of low energy, high temperature nitrogen ion-implanted AISI 304 stainless steel”

Flege, S. (2012)
Comment on: “Corrosion behaviour of low energy, high temperature nitrogen ion-implanted AISI 304 stainless steel”.
In: Pramana, 78 (2)
doi: 10.1007/s12043-011-0228-7
Artikel, Bibliographie

Kurzbeschreibung (Abstract)

Ghoranneviss et al [1] have reported on nitrogen implantation into stainless steel and presented a secondary ion mass spectrometry (SIMS) measurement of the N and the CrN intensities with sputter time in figure 2. The experimental part described the measurement conditions, mentioning that Cs+ primary ions were used and negative secondary ions were detected. A difference in the distribution of the CrN and the alleged N signal was observed and attributed to CrN acting as a diffusion barrier for nitrogen diffusion. It may be noted here that nitrogen does not form stable elemental negative ions [2] and is thus not detectable in SIMS measurements as N− [3]. Hence the signal with a mass-to-charge ratio of 14 is most likely some interference but definitely not nitrogen.

Typ des Eintrags: Artikel
Erschienen: 2012
Autor(en): Flege, S.
Art des Eintrags: Bibliographie
Titel: Comment on: “Corrosion behaviour of low energy, high temperature nitrogen ion-implanted AISI 304 stainless steel”
Sprache: Englisch
Publikationsjahr: 1 Februar 2012
Verlag: Springer-Verlag
Titel der Zeitschrift, Zeitung oder Schriftenreihe: Pramana
Jahrgang/Volume einer Zeitschrift: 78
(Heft-)Nummer: 2
DOI: 10.1007/s12043-011-0228-7
Kurzbeschreibung (Abstract):

Ghoranneviss et al [1] have reported on nitrogen implantation into stainless steel and presented a secondary ion mass spectrometry (SIMS) measurement of the N and the CrN intensities with sputter time in figure 2. The experimental part described the measurement conditions, mentioning that Cs+ primary ions were used and negative secondary ions were detected. A difference in the distribution of the CrN and the alleged N signal was observed and attributed to CrN acting as a diffusion barrier for nitrogen diffusion. It may be noted here that nitrogen does not form stable elemental negative ions [2] and is thus not detectable in SIMS measurements as N− [3]. Hence the signal with a mass-to-charge ratio of 14 is most likely some interference but definitely not nitrogen.

Fachbereich(e)/-gebiet(e): 11 Fachbereich Material- und Geowissenschaften
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Materialanalytik
Hinterlegungsdatum: 14 Jan 2013 09:57
Letzte Änderung: 17 Sep 2018 12:28
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