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Probing the Nature of Defects in Graphene by Raman Spectroscopy

Eckmann, Axel ; Felten, Alexandre ; Mishchenko, Artem ; Britnell, Liam ; Krupke, Ralph ; Novoselov, Kostya S. ; Casiraghi, Cinzia (2012)
Probing the Nature of Defects in Graphene by Raman Spectroscopy.
In: Nano Letters, 12 (8)
doi: 10.1021/nl300901a
Artikel, Bibliographie

Kurzbeschreibung (Abstract)

Raman spectroscopy is able to probe disorder in graphene through defect-activated peaks. It is of great interest to link these features to the nature of disorder. Here we present a detailed analysis of the Raman spectra of graphene containing different type of defects. We found that the intensity ratio of the D and D′ peak is maximum (13) for sp3-defects, it decreases for vacancy-like defects (7), and it reaches a minimum for boundaries in graphite (3.5). This makes Raman Spectroscopy a powerful tool to fully characterize graphene.

Typ des Eintrags: Artikel
Erschienen: 2012
Autor(en): Eckmann, Axel ; Felten, Alexandre ; Mishchenko, Artem ; Britnell, Liam ; Krupke, Ralph ; Novoselov, Kostya S. ; Casiraghi, Cinzia
Art des Eintrags: Bibliographie
Titel: Probing the Nature of Defects in Graphene by Raman Spectroscopy
Sprache: Englisch
Publikationsjahr: 5 Juli 2012
Titel der Zeitschrift, Zeitung oder Schriftenreihe: Nano Letters
Jahrgang/Volume einer Zeitschrift: 12
(Heft-)Nummer: 8
DOI: 10.1021/nl300901a
Kurzbeschreibung (Abstract):

Raman spectroscopy is able to probe disorder in graphene through defect-activated peaks. It is of great interest to link these features to the nature of disorder. Here we present a detailed analysis of the Raman spectra of graphene containing different type of defects. We found that the intensity ratio of the D and D′ peak is maximum (13) for sp3-defects, it decreases for vacancy-like defects (7), and it reaches a minimum for boundaries in graphite (3.5). This makes Raman Spectroscopy a powerful tool to fully characterize graphene.

Freie Schlagworte: Graphene; Raman spectroscopy; defects; conductive AFM
Fachbereich(e)/-gebiet(e): 11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Molekulare Nanostrukturen
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft
11 Fachbereich Material- und Geowissenschaften
Hinterlegungsdatum: 16 Aug 2012 07:08
Letzte Änderung: 05 Mär 2013 10:02
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