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Polymer-derived SiBCN ceramic and their potential application for high temperature membranes

Hauser, Ralf and Nahar-Borchard, Saifun and Riedel, Ralf and Ikuhara, Yumi H. and Iwamoto, Yuji (2012):
Polymer-derived SiBCN ceramic and their potential application for high temperature membranes.
In: JOURNAL OF THE CERAMIC SOCIETY OF JAPAN, CERAMIC SOC JAPAN-NIPPON SERAMIKKUSU KYOKAI, 2-22-17 HYAKUNIN-CHO SHINJUKU-KU, TOKYO, 169, JAPAN, pp. 524-528, 114, (1330), ISSN 0914-5400,
[Article]

Abstract

A novel preceramic polymer suitable to form a SiBCN ceramic was synthesized by hydroboration reaction of 1,3,5-trivinyl-1,3,5-trimethyl-cyclotrisilazane with borane dimethylsulphide. The obtained polymer denoted as poly (borosilazane) was characterised by FT-IR and NMR spectroscopy and its thermal stability was studied by thermal gravimetric analysis in combination with in situ mass spectrometry (TG/MS). The polymer-to-ceramic transformation was achieved at 1050 degrees C in inert argon atmosphere yielding black and X-ray amorphous SiBCN ceramics thermally stable up to 1800 degrees C. Using the dip-coating technique, a SiBCN ceramic thin film was formed on a porous alumina substrate. N-2 sorption isotherm analysis revealed that the thin film contained a small amount of micropores of about 0.6 nm in diameter, as well as mesopores between 2.7 and 6 nm in size. The total pore volume was found to be about three orders of magnitude smaller than that of a hydrogen permselective amorphous silica membrane derived from polysilazane. These results indicated potential application of the SiBCN thin film as a molecular sieve membrane suitable for high-temperature separation of small gas molecules like hydrogen below 0.3 nm in size.

Item Type: Article
Erschienen: 2012
Creators: Hauser, Ralf and Nahar-Borchard, Saifun and Riedel, Ralf and Ikuhara, Yumi H. and Iwamoto, Yuji
Title: Polymer-derived SiBCN ceramic and their potential application for high temperature membranes
Language: English
Abstract:

A novel preceramic polymer suitable to form a SiBCN ceramic was synthesized by hydroboration reaction of 1,3,5-trivinyl-1,3,5-trimethyl-cyclotrisilazane with borane dimethylsulphide. The obtained polymer denoted as poly (borosilazane) was characterised by FT-IR and NMR spectroscopy and its thermal stability was studied by thermal gravimetric analysis in combination with in situ mass spectrometry (TG/MS). The polymer-to-ceramic transformation was achieved at 1050 degrees C in inert argon atmosphere yielding black and X-ray amorphous SiBCN ceramics thermally stable up to 1800 degrees C. Using the dip-coating technique, a SiBCN ceramic thin film was formed on a porous alumina substrate. N-2 sorption isotherm analysis revealed that the thin film contained a small amount of micropores of about 0.6 nm in diameter, as well as mesopores between 2.7 and 6 nm in size. The total pore volume was found to be about three orders of magnitude smaller than that of a hydrogen permselective amorphous silica membrane derived from polysilazane. These results indicated potential application of the SiBCN thin film as a molecular sieve membrane suitable for high-temperature separation of small gas molecules like hydrogen below 0.3 nm in size.

Journal or Publication Title: JOURNAL OF THE CERAMIC SOCIETY OF JAPAN
Volume: 114
Number: 1330
Publisher: CERAMIC SOC JAPAN-NIPPON SERAMIKKUSU KYOKAI, 2-22-17 HYAKUNIN-CHO SHINJUKU-KU, TOKYO, 169, JAPAN
Uncontrolled Keywords: polymer-derived ceramic (PDC), SiBCN ceramic, hydroboration, poly (borosilazane), dip-coating, membrane
Divisions: 11 Department of Materials and Earth Sciences > Material Science > Dispersive Solids
11 Department of Materials and Earth Sciences > Material Science
11 Department of Materials and Earth Sciences
Date Deposited: 20 Apr 2012 10:57
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